FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2560334893> ?p ?o ?g. }

• W2560334893 endingPage "54" @default.
• W2560334893 startingPage "48" @default.
• W2560334893 abstract "A novel solid-liquid two-phase system was developed for the chiral separation of racemic phenylalanine with new dication imidazolium-based chiral ionic liquids. Preliminary experiments showed distinct enantioselectivity in amino acid extraction with the novel solid-liquid two-phase system, more L-enantiomer of amino acid cooperatively interacted with ionic liquids and copper ions to be the solid phase. Various factors, including the alkyl chain length of cations of ionic liquids, the amount of copper acetate, the ratio of n(ILs)/n(Cu2+), the amount of water and racemic phenylalanine, the resolution time together with the resolution temperature, were systematically investigated for their influence on resolution efficiency. The results showed that, under a certain condition, the enantiomeric excess value and the yield of phenylalanine in liquid phase (mainly containing D-enantiomer) were 67.8% and 96.5%, the enantiomeric excess value and the yield of phenylalanine in solid phase (mainly containing L-enantiomer) were 99.2% and 85.2%. Finally, 2D NMR technology, infrared spectroscopy and molecular simulation method were used to study the interaction mechanism. The results indicated that L-enantiomer of phenylalanine interacts more strongly with chiral ILs and Cu2+. The novel system has characteristics of free-organic solvent, simple operation, fast separation process and very high resolution efficiency for racemic phenylalanine. This work could provide a new and alternative resolution approach for other chiral separations." @default.
• W2560334893 created "2016-12-16" @default.
• W2560334893 creator A5013277489 @default.
• W2560334893 creator A5024915644 @default.
• W2560334893 creator A5055819435 @default.
• W2560334893 creator A5082805505 @default.
• W2560334893 creator A5083187697 @default.
• W2560334893 date "2017-01-01" @default.
• W2560334893 modified "2023-09-24" @default.
• W2560334893 title "High resolution of racemic phenylalanine with dication imidazolium-based chiral ionic liquids in a solid-liquid two-phase system" @default.
• W2560334893 cites W1577243838 @default.
• W2560334893 cites W1724141729 @default.
• W2560334893 cites W1917274640 @default.
• W2560334893 cites W1964352506 @default.
• W2560334893 cites W1964973935 @default.
• W2560334893 cites W1965902062 @default.
• W2560334893 cites W1972643212 @default.
• W2560334893 cites W1977618051 @default.
• W2560334893 cites W1979116277 @default.
• W2560334893 cites W1987231410 @default.
• W2560334893 cites W1994420359 @default.
• W2560334893 cites W1994600867 @default.
• W2560334893 cites W1994642341 @default.
• W2560334893 cites W2006690803 @default.
• W2560334893 cites W2008900331 @default.
• W2560334893 cites W2019110305 @default.
• W2560334893 cites W2019747015 @default.
• W2560334893 cites W2021560264 @default.
• W2560334893 cites W2027583385 @default.
• W2560334893 cites W2033018799 @default.
• W2560334893 cites W2044882633 @default.
• W2560334893 cites W2051625128 @default.
• W2560334893 cites W2053591647 @default.
• W2560334893 cites W2069480559 @default.
• W2560334893 cites W2084116993 @default.
• W2560334893 cites W2093597250 @default.
• W2560334893 cites W2106861186 @default.
• W2560334893 cites W2120483697 @default.
• W2560334893 cites W253105081 @default.
• W2560334893 cites W2952145651 @default.
• W2560334893 cites W2952439997 @default.
• W2560334893 doi "https://doi.org/10.1016/j.chroma.2016.12.012" @default.
• W2560334893 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27979313" @default.
• W2560334893 hasPublicationYear "2017" @default.
• W2560334893 type Work @default.
• W2560334893 sameAs 2560334893 @default.
• W2560334893 citedByCount "21" @default.
• W2560334893 countsByYear W25603348932017 @default.
• W2560334893 countsByYear W25603348932018 @default.
• W2560334893 countsByYear W25603348932019 @default.
• W2560334893 countsByYear W25603348932020 @default.
• W2560334893 countsByYear W25603348932021 @default.
• W2560334893 countsByYear W25603348932022 @default.
• W2560334893 countsByYear W25603348932023 @default.
• W2560334893 crossrefType "journal-article" @default.
• W2560334893 hasAuthorship W2560334893A5013277489 @default.
• W2560334893 hasAuthorship W2560334893A5024915644 @default.
• W2560334893 hasAuthorship W2560334893A5055819435 @default.
• W2560334893 hasAuthorship W2560334893A5082805505 @default.
• W2560334893 hasAuthorship W2560334893A5083187697 @default.
• W2560334893 hasConcept C134121241 @default.
• W2560334893 hasConcept C146686406 @default.
• W2560334893 hasConcept C154881586 @default.
• W2560334893 hasConcept C156217769 @default.
• W2560334893 hasConcept C161790260 @default.
• W2560334893 hasConcept C16838498 @default.
• W2560334893 hasConcept C178790620 @default.
• W2560334893 hasConcept C185592680 @default.
• W2560334893 hasConcept C191897082 @default.
• W2560334893 hasConcept C192562407 @default.
• W2560334893 hasConcept C2777431362 @default.
• W2560334893 hasConcept C3141732 @default.
• W2560334893 hasConcept C44280652 @default.
• W2560334893 hasConcept C47849319 @default.
• W2560334893 hasConcept C486523 @default.
• W2560334893 hasConcept C515207424 @default.
• W2560334893 hasConcept C55493867 @default.
• W2560334893 hasConceptScore W2560334893C134121241 @default.
• W2560334893 hasConceptScore W2560334893C146686406 @default.
• W2560334893 hasConceptScore W2560334893C154881586 @default.
• W2560334893 hasConceptScore W2560334893C156217769 @default.
• W2560334893 hasConceptScore W2560334893C161790260 @default.
• W2560334893 hasConceptScore W2560334893C16838498 @default.
• W2560334893 hasConceptScore W2560334893C178790620 @default.
• W2560334893 hasConceptScore W2560334893C185592680 @default.
• W2560334893 hasConceptScore W2560334893C191897082 @default.
• W2560334893 hasConceptScore W2560334893C192562407 @default.
• W2560334893 hasConceptScore W2560334893C2777431362 @default.
• W2560334893 hasConceptScore W2560334893C3141732 @default.
• W2560334893 hasConceptScore W2560334893C44280652 @default.
• W2560334893 hasConceptScore W2560334893C47849319 @default.
• W2560334893 hasConceptScore W2560334893C486523 @default.
• W2560334893 hasConceptScore W2560334893C515207424 @default.
• W2560334893 hasConceptScore W2560334893C55493867 @default.
• W2560334893 hasLocation W25603348931 @default.
• W2560334893 hasLocation W25603348932 @default.
• W2560334893 hasOpenAccess W2560334893 @default.
• W2560334893 hasPrimaryLocation W25603348931 @default.

• next