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• W2560358222 abstract "Abstract The coordination of N‐heterocyclic carbene (NHC) ligands to the surface of 3.7 nm palladium nanoparticles (PdNPs) can be unambiguously established by observation of Knight shift (KS) in the 13 C resonance of the carbenic carbon. In order to validate this coordination, PdNPs with sizes ranging from 1.3 to 4.8 nm were prepared by thermal decomposition or reduction with CO of a dimethyl NHC Pd II complex. NMR studies after 13 CO adsorption established that the KS shifts the 13 C resonances of the chemisorbed molecules several hundreds of ppm to high frequencies only when the particle exceeds a critical size of around 2 nm. Finally, the resonance of a carbenic carbon is reported to be Knight‐shifted to 600 ppm for 13 C‐labelled NHCs bound to PdNPs of 3.7 nm. The observation of these very broad KS resonances was facilitated by using Car–Purcell–Meiboom–Gill (CPMG) echo train acquisition NMR experiments." @default.
• W2560358222 created "2016-12-16" @default.
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• W2560358222 date "2016-12-09" @default.
• W2560358222 modified "2023-10-02" @default.
• W2560358222 title "Knight Shift in ¹³ C NMR Resonances Confirms the Coordination of N‐Heterocyclic Carbene Ligands to Water‐Soluble Palladium Nanoparticles" @default.
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• W2560358222 doi "https://doi.org/10.1002/anie.201610251" @default.
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