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- W2560370396 abstract "The PBE/TZ2P method was used to study a concerted �dimerization reaction of 1�sila� cycloprop�2�enes having substituents with different electron effects. The corresponding reac� tion channels were founds in all the cases, that indicated a general character of this reaction. The reaction barriers varied from moderately high to extremely low. The suggestions made earlier on a possibility for this process to take place in the course of the reaction of silylenes with alkynes at elevated temperature were quantitatively confirmed for the first time. The influence of substituents on the barrier heights and exothermicity of �dimerization of 1�silacycloprop�2� enes was studied. The �dimerization reaction of 1�silacycloprop�2�enes is one of a few exam� ples of metathesis of �bonds in the absence of transition metal complexes." @default.
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- W2560370396 date "2013-01-01" @default.
- W2560370396 modified "2023-09-24" @default.
- W2560370396 title "Quantum chemical study of dimerization reaction of 1silacycloprop2enes" @default.
- W2560370396 hasPublicationYear "2013" @default.
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