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- W2560375771 abstract "Abstract A series of supported membranes with zeolite FAU either as a thin layer or as powder in Matrimid as Mixed Matrix Membrane (MMM) have been prepared and evaluated in the H 2 /CO 2 separation. In addition to neat NaX membrane layers, we developed two novel composite materials, namely FAU/Matrimid ® Mixed Matrix Membranes (MMMs) as well as NaX/Matrimid ® multilayer/sandwich membranes, all of them supported by porous alumina plates. The influence of different pre-synthetic support modifications (APTES = 3-aminopropyltrietoxysilane, PDA = polydopamine) on the quality of neat supported NaX membranes grown as layer on these modified supports has been investigated studying the H 2 /CO 2 separation performance. It could be shown that NaX membrane layers grown on modified supports show an remarkably increased quality and correspondingly higher H 2 /CO 2 separation factors α (H 2 /CO 2 ) (α = 8.0 for neat NaX, α = 8.9 for NaX/APTES and α = 10.3 for NaX/PDA). In the preparation of MMMs, the separation performance could be improved by ion exchanged Na-FAU powders. Exchanging the Na + of the as-synthesized NaX particles for metal ions with higher ionic potentials like Co 2+ , results in enhanced mixed gas separation factors α in the H 2 /CO 2 separation (NaX/Matrimid ® MMM α = 4.0 and CoX/Matrimid ® MMM α = 5.6)." @default.
- W2560375771 created "2016-12-16" @default.
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- W2560375771 date "2017-01-01" @default.
- W2560375771 modified "2023-09-24" @default.
- W2560375771 title "On comparing permeation through Matrimid®-based mixed matrix and multilayer sandwich FAU membranes: H2/CO2 separation, support functionalization and ion exchange" @default.
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- W2560375771 doi "https://doi.org/10.1016/j.ijhydene.2016.10.161" @default.
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