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- W2560484763 abstract "1,2,3,4-Tetrahydro-β-carbolines (THBC) are an important class of indole-containing alkaloids with biological and medicinal importance. This report describes the use of a Pd-catalyzed asymmetric allylic alkylation (AAA, Trost reaction) to generate THBC derivatives as well as the synthesis of tetrahydro-γ-carbolines (THGCs). A thorough screening of ‘privileged’ P,P- and P,N-ligands was done and the optimum conditions employed Li2CO3 as the base. Indole substrates with electron-donating and electron-withdrawing groups were tested, with the former giving significantly higher enantiomeric excesses." @default.
- W2560484763 created "2016-12-16" @default.
- W2560484763 date "2006-03-24" @default.
- W2560484763 modified "2023-09-25" @default.
- W2560484763 title "Tetrahydro-β-Carbolines and Via Pd-Catalyzed Intramolecular Allylic Alkylation" @default.
- W2560484763 doi "https://doi.org/10.1055/s-2006-934334" @default.
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