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- W2560673798 abstract "Chiral nano-assemblies with amplified optical activity have attracted particular interest for their potential application in photonics, sensing and catalysis. Yet it still remains a great challenge to realize their real applications due to the instability of these assembled nanostructures. Herein, we demonstrate a facile and efficient method to fabricate ultrastable chiral nanostructures with strong chiroptical properties. In these novel chiral nanostructures, side-by-side assembly of chiral cysteine modified gold nanorods serves as core while mesoporous silica acts as shell. The chiral core-shell nanostructures exhibit evident plasmonic circular dichroism (CD) response originating from the chiral core. Impressively, such plasmonic CD signals can be easily manipulated by changing the number as well as the aspect ratio of Au nanorods in the assemblies located at the core. Also thanks to the stabilization effect of silica shells, the chiroptical performance of these core-shell nanostructures is significantly improved in different chemical environment." @default.
- W2560673798 created "2016-12-16" @default.
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- W2560673798 date "2015-01-01" @default.
- W2560673798 modified "2023-09-27" @default.
- W2560673798 title "Ultrastable Gold Nanorod Assembly@Silica Core-shell Nanostructures with Enhanced Chiroptical Properties" @default.
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