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- W2560932349 abstract "Hydrocarboxylation of allyl cyanide with monodentate phosphane systems (palladium/triphenylphosphane and protic acid co-catalyst) gave branched 3-cyano-2-methylpropanoic acid chemo- and regioselectively, while with bidentate systems (palladium/ DPEphos and protic acid co-catalyst) it gave linear 4-cyanobutanoic acid chemo- and regioselectively. 3-Cyano-2-methylpropanoic acid and 4-cyanobutanoic acid were isolated in high yields as carboxylic acids and purified as benzyl esters. No isomerisation of allyl cyanide to crotononitrile or its carbonylated derivatives was observed in any case. In parallel experiments, deuterocarboxylation in the same conditions gave the corresponding deuterated products, that were analyzed by MS and ²H NMR: only d₀, d₁ and d₂ products were detected. Deuterium entered the β and γ-CN positions of the products, but never in the α position." @default.
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- W2560932349 date "2017-02-20" @default.
- W2560932349 modified "2023-09-23" @default.
- W2560932349 title "Selective Catalytic Hydrocarboxylation and Deuterocarboxylation of Allyl Cyanide to Cyanobutanoic Acids with Monodentate and Bidentate Phosphines" @default.
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- W2560932349 doi "https://doi.org/10.1002/cctc.201601436" @default.
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