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• W2560954902 abstract "The trivalent ate complex [Cp* 2 CeCl 2 K(thf)] (Cp* = C 5 Me 5 ) was used in a diverse set of salt metathesis reactions. Equimolar reactions with LiN i Pr 2 , LiN(SiHMe 2 ) 2 , KN(SiMe 3 ) 2 , and LiCH 2 C 6 H 4 ‐ o ‐NMe 2 gave the alkali metal‐free complexes [Cp* 2 Ce(N i Pr 2 )], [Cp* 2 Ce{N(SiHMe 2 ) 2 }], [Cp* 2 Ce{N(SiMe 3 ) 2 }], and [Cp* 2 Ce(CH 2 C 6 H 4 ‐ o ‐NMe 2 )]. Employing [Cp* 2 CeCl 2 K(thf)] and KC≡C t Bu in a 1:2 ratio produced a mixture of [Cp* 2 Ce(C≡C t Bu) 2 Li(thf)] and [Cp* 2 Ce(C≡C t Bu)] 2 (LiCl) that was difficult to separate. The reaction of [Cp* 2 CeCl 2 Li(Et 2 O)] with 2 equiv. of LiC≡CPh involved Cp* displacement and formation of the tetrametallic half‐sandwich complex [Cp*Ce(C≡CPh) 2 ] 4 (LiCl). All complexes were characterized by single‐crystal X‐ray structure analysis. The distinct terminal bonding behavior of the similarly sized N i Pr 2 and N(SiHMe 2 ) 2 , of which the latter revealed a strong Ce ··· HSi β‐diagostic interaction, is supported by distinct paramagnetic shifts of the amido substituents in the 1 H NMR spectra. As examples, [Cp* 2 Ce{N(SiHMe 2 ) 2 }] and [Cp* 2 Ce(C≡C t Bu) 2 Li(thf)] were tested for oxidation reactions with 1,4‐benzoquinone and Ph 3 CCl, respectively." @default.
• W2560954902 created "2017-01-06" @default.
• W2560954902 creator A5005201385 @default.
• W2560954902 creator A5013197929 @default.
• W2560954902 date "2017-02-24" @default.
• W2560954902 modified "2023-10-09" @default.
• W2560954902 title "Pentamethylcyclopentadienyl‐Supported Cerocene(III) Complexes" @default.
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• W2560954902 doi "https://doi.org/10.1002/ejic.201601404" @default.
• W2560954902 hasPublicationYear "2017" @default.
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