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- W2561043982 abstract "Abstract The corrosion rate of Mg indicates a strong crystallographic dependence in chloride-containing, alkaline environments that correlates inversely with oxide film thickness. In contrast, a different crystallographic orientation dependency is observed initially during open circuit corrosion in non-chloride containing, near neutral pH buffered, chelating environments such as Tris(hydroxymethyl)aminomethane (TRIS) and Ethylenediaminetetraacetic (EDTA) which minimize air-formed MgO oxides. The origins of the differences in the rates of the coupled corrosion processes as a function of crystallographic orientation were investigated utilizing electrochemical impedance spectroscopy (EIS) and Raman vibrational spectroscopy. High frequency constant phase elements (CPEs) were exploited to determine oxide thicknesses as a function of crystal orientation. In unbuffered NaCl, open circuit corrosion was faster on basal planes while lower corrosion rates were observed on low index, prismatic and pyramidal planes. This variation in rate with crystallographic orientation in 0.6 M NaCl was interpreted to depend on the MgO and Mg(OH)2 film thicknesses as a function of orientation. In particular, crystal planes with a lower MgO/Mg(OH)2 thickness corroded at higher rates as assessed in-situ by EIS and suggested by Raman spectroscopy. The crystallographic orientation dependence of corrosion seen initially upon exposure in the buffered neutral pH environments corresponded with crystal facet surface energy for bare Mg but this trend disappeared with exposure time and Mg(OH)2 films were then detected." @default.
- W2561043982 created "2017-01-06" @default.
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- W2561043982 date "2017-02-01" @default.
- W2561043982 modified "2023-10-06" @default.
- W2561043982 title "Effect of Crystallographic Orientation on the Corrosion of Magnesium: Comparison of Film Forming and Bare Crystal Facets using Electrochemical Impedance and Raman Spectroscopy" @default.
- W2561043982 cites W1554276091 @default.
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- W2561043982 cites W1765117560 @default.
- W2561043982 cites W1772374297 @default.
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- W2561043982 cites W1968033101 @default.
- W2561043982 cites W1968108776 @default.
- W2561043982 cites W1969526567 @default.
- W2561043982 cites W1973393580 @default.
- W2561043982 cites W1974727023 @default.
- W2561043982 cites W1977703321 @default.
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- W2561043982 cites W1978792874 @default.
- W2561043982 cites W1979273600 @default.
- W2561043982 cites W1980927807 @default.
- W2561043982 cites W1987577919 @default.
- W2561043982 cites W1989352103 @default.
- W2561043982 cites W1993265556 @default.
- W2561043982 cites W1994633522 @default.
- W2561043982 cites W2001632517 @default.
- W2561043982 cites W2001702389 @default.
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- W2561043982 cites W2034412405 @default.
- W2561043982 cites W2034792823 @default.
- W2561043982 cites W2035037549 @default.
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- W2561043982 doi "https://doi.org/10.1016/j.electacta.2016.12.107" @default.
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