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• W2561590561 abstract "Plasmonic enhancement of Raman scattering intensity is a promising method to obtain vibrational information on molecule-substrate interactions with high detection sensitivity. Although recent advancement in nanotechnology has enabled us to control plasmon resonance property of metal nanostructures, it is still difficult to manage atomic surface features of metal nanostructures, which significantly affect molecule-substrate interactions. In this chapter, influence of atomic local environment to Raman spectral appearance is presented using atomically defined metal substrates. Excitation of localized plasmon resonance on such a planar metal surface is achieved by forming sphere-plane type nano-gap structures on the substrate. Both vibrational and electronic structures at metal-molecule interface are compared on various metal substrates including bulk Au and Pt with different orientations or catalytic metal monolayers." @default.
• W2561590561 created "2017-01-06" @default.
• W2561590561 creator A5062279039 @default.
• W2561590561 date "2016-01-01" @default.
• W2561590561 modified "2023-09-30" @default.
• W2561590561 title "Plasmon Enhanced Raman Scattering from Molecular Adsorbates on Atomically Defined Planar Metal Surfaces" @default.
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• W2561590561 doi "https://doi.org/10.1021/bk-2016-1246.ch003" @default.
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