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- W2561644504 abstract "The kinetics and acid-base properties of the catalytic decomposition of 2-butanol over magnesium oxide, zirconium dioxide and vanadium pentoxide have been investigated using low-pressure steady-state temperature-programmed reaction spectroscopy. Basic catalysts are typically active in the dehydrogenation of secondary alcohols, while acidic catalysts are typically active in the dehydration of secondary alcohols. The catalysts investigated in this work, MgO, ZrO2 and V2O5 are respectively basic, amphoteric and acidic in nature. Products resulting from the exposure of 2-butanol to these metal oxides and the kinetics of dehydration to butene and dehydrogenation to 2-butanone are reported. V2O5 was found to show the highest activity towards 2-butanol dehydration, while MgO and ZrO2 were more active for dehydrogenation. Trace products (butane, acetone and crotonic acid) and the complete oxidation products CO2 and H2O were also apparent for each catalyst." @default.
- W2561644504 created "2017-01-06" @default.
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- W2561644504 date "2010-01-01" @default.
- W2561644504 modified "2023-09-23" @default.
- W2561644504 title "Investigations into the Acid-base Properties of 2-Butanol Decomposition over Metal Oxides" @default.
- W2561644504 hasPublicationYear "2010" @default.
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