Matches in SemOpenAlex for { <https://semopenalex.org/work/W2561663960> ?p ?o ?g. }
- W2561663960 endingPage "213" @default.
- W2561663960 startingPage "213" @default.
- W2561663960 abstract "Palladium and ruthenium nanoparticles have been prepared following the organometallic precursor decomposition methodology, under dihydrogen pressure and in the presence of borane protected P-stereogenic phosphines. NMR (Nuclear Magnetic Resonance) monitoring of the corresponding syntheses has permitted to determine the optimal metal/ligand ratio for leading to small and well-dispersed nanoparticles. Exchange ligand reactions of the as-prepared materials have proven the strong interaction of the phosphines with the metal surface; only oxidative treatment using hydrogen peroxide could release the phosphine-based stabiliser from the metal surface. Pd and Ru nanoparticles have been evaluated in hydrogenation reactions, confirming the robustness of the stabilisers, which selectively permitted the hydrogenation of exocyclic C=C bonds, preventing the coordination of the aromatic rings and as a result, their hydrogenation." @default.
- W2561663960 created "2017-01-06" @default.
- W2561663960 creator A5009244114 @default.
- W2561663960 creator A5018178541 @default.
- W2561663960 creator A5032904273 @default.
- W2561663960 creator A5037072491 @default.
- W2561663960 creator A5040028609 @default.
- W2561663960 creator A5055752156 @default.
- W2561663960 creator A5056975757 @default.
- W2561663960 date "2016-12-20" @default.
- W2561663960 modified "2023-09-30" @default.
- W2561663960 title "P-Stereogenic Phosphines for the Stabilisation of Metal Nanoparticles. A Surface State Study" @default.
- W2561663960 cites W1955959430 @default.
- W2561663960 cites W1970097675 @default.
- W2561663960 cites W1976085475 @default.
- W2561663960 cites W1981023232 @default.
- W2561663960 cites W1981065216 @default.
- W2561663960 cites W1981379828 @default.
- W2561663960 cites W1983659117 @default.
- W2561663960 cites W1987775798 @default.
- W2561663960 cites W1988373554 @default.
- W2561663960 cites W2003983566 @default.
- W2561663960 cites W2009370533 @default.
- W2561663960 cites W2010386719 @default.
- W2561663960 cites W2010790046 @default.
- W2561663960 cites W2014510944 @default.
- W2561663960 cites W2022704527 @default.
- W2561663960 cites W2025443759 @default.
- W2561663960 cites W2030441781 @default.
- W2561663960 cites W2031980730 @default.
- W2561663960 cites W2040353222 @default.
- W2561663960 cites W2041334706 @default.
- W2561663960 cites W2051316929 @default.
- W2561663960 cites W2053735116 @default.
- W2561663960 cites W2055934151 @default.
- W2561663960 cites W2056716426 @default.
- W2561663960 cites W2057162458 @default.
- W2561663960 cites W2061030258 @default.
- W2561663960 cites W2062430101 @default.
- W2561663960 cites W2075533159 @default.
- W2561663960 cites W2076360770 @default.
- W2561663960 cites W2079654266 @default.
- W2561663960 cites W2098780685 @default.
- W2561663960 cites W2099183715 @default.
- W2561663960 cites W2110730693 @default.
- W2561663960 cites W2114442651 @default.
- W2561663960 cites W2120634307 @default.
- W2561663960 cites W2131209492 @default.
- W2561663960 cites W2144367036 @default.
- W2561663960 cites W2152363678 @default.
- W2561663960 cites W2165003049 @default.
- W2561663960 cites W2167577455 @default.
- W2561663960 cites W2206669259 @default.
- W2561663960 cites W2226694881 @default.
- W2561663960 cites W2321983796 @default.
- W2561663960 cites W2329497066 @default.
- W2561663960 cites W2950798614 @default.
- W2561663960 cites W4239329501 @default.
- W2561663960 cites W4376848822 @default.
- W2561663960 cites W624677655 @default.
- W2561663960 doi "https://doi.org/10.3390/catal6120213" @default.
- W2561663960 hasPublicationYear "2016" @default.
- W2561663960 type Work @default.
- W2561663960 sameAs 2561663960 @default.
- W2561663960 citedByCount "2" @default.
- W2561663960 countsByYear W25616639602019 @default.
- W2561663960 countsByYear W25616639602022 @default.
- W2561663960 crossrefType "journal-article" @default.
- W2561663960 hasAuthorship W2561663960A5009244114 @default.
- W2561663960 hasAuthorship W2561663960A5018178541 @default.
- W2561663960 hasAuthorship W2561663960A5032904273 @default.
- W2561663960 hasAuthorship W2561663960A5037072491 @default.
- W2561663960 hasAuthorship W2561663960A5040028609 @default.
- W2561663960 hasAuthorship W2561663960A5055752156 @default.
- W2561663960 hasAuthorship W2561663960A5056975757 @default.
- W2561663960 hasBestOaLocation W25616639601 @default.
- W2561663960 hasConcept C116569031 @default.
- W2561663960 hasConcept C134195300 @default.
- W2561663960 hasConcept C146686406 @default.
- W2561663960 hasConcept C155672457 @default.
- W2561663960 hasConcept C161790260 @default.
- W2561663960 hasConcept C170493617 @default.
- W2561663960 hasConcept C171250308 @default.
- W2561663960 hasConcept C178790620 @default.
- W2561663960 hasConcept C185592680 @default.
- W2561663960 hasConcept C188027245 @default.
- W2561663960 hasConcept C192562407 @default.
- W2561663960 hasConcept C21951064 @default.
- W2561663960 hasConcept C2777716191 @default.
- W2561663960 hasConcept C2778826510 @default.
- W2561663960 hasConcept C2780345374 @default.
- W2561663960 hasConcept C31903555 @default.
- W2561663960 hasConcept C502130503 @default.
- W2561663960 hasConcept C533411734 @default.
- W2561663960 hasConcept C544153396 @default.
- W2561663960 hasConcept C55493867 @default.
- W2561663960 hasConcept C555196967 @default.
- W2561663960 hasConcept C75473681 @default.