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• W2561752616 abstract "High hydrogen content and long-term stability in aqueous solutions make ammonia-borane (AB) a promising hydrogen-storage material. It is highly attractive but still challenging to develop efficient catalysts for real-time and controllable hydrogen release from AB solution under mild conditions. Herein, we describe the use of a three-dimensional hierarchical Cu(OH)2@Co2CO3(OH)2 core-shell nanowire array on copper foam (denoted as Cu(OH)2@Co2CO3(OH)2/CF) as a highly efficient catalyst for hydrolytic dehydrogenation of AB. The Cu(OH)2@Co2CO3(OH)2/CF works as an on/off switch for on-demand hydrogen generation with a low activation energy of 44.3 KJ mol-1 and a turnover frequency of 39.72 mol(H2)/mol(cat.)/min. It also maintains activity and integration after long-term usage." @default.
• W2561752616 created "2017-01-06" @default.
• W2561752616 creator A5010577284 @default.
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• W2561752616 date "2016-12-21" @default.
• W2561752616 modified "2023-10-18" @default.
• W2561752616 title "Self-supported Cu(OH)2@Co2CO3(OH)2 core–shell nanowire array as a robust catalyst for ammonia-borane hydrolysis" @default.
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• W2561752616 doi "https://doi.org/10.1088/1361-6528/28/4/045606" @default.
• W2561752616 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/28000614" @default.
• W2561752616 hasPublicationYear "2016" @default.
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