Matches in SemOpenAlex for { <https://semopenalex.org/work/W2562022035> ?p ?o ?g. }
Showing items 1 to 93 of
93
with 100 items per page.
- W2562022035 endingPage "138" @default.
- W2562022035 startingPage "131" @default.
- W2562022035 abstract "Abstract 2-R-2H-Tetrazol-5-ylacetic acids (R = iso-Pr, tert-Bu, CH2COOH) (1a–c) react with PdCl2 in 5% (w/w) MeOH in 1 M HCl furnishing the palladium(II) water soluble complexes trans-[PdCl2L2] (2a–c). In the presence of EtOH in the reaction mixture, esterification of the tetrazolylacetoxy groups occurs leading to trans-[PdCl2(ethyl 2-R-2H-tetrazol-5-ylacetate)2] (3a–c). In the case of reaction of 2-tert-butyl-tetrazol-5-ylacetic acid 1b with PdCl2 increasing of the proportion of methanol up to 50% (w/w) led to the esterification to give trans-[PdCl2(methyl 2-tert-butyl-tetrazol-5-ylacetate)2] 4b. Complexation of isomeric 5-methyl-1H-tetrazol-1-ylacetic acid 5 with PdCl2 at the same conditions leads to trans-[PdCl2(5-methyl-1H-tetrazol-1-ylacetic acid)2] 6 and trans-[PdCl2(ethyl 2-(5-methyl-1H-tetrazol-1-yl)acetate)2] 7. The complexes obtained were characterized by HRESI+-MS, 1H, 13C{1H} NMR, and IR spectroscopies as well as by X-ray diffraction (for 2a, 3a, 3b, 4b and 6·H2O). According DSC/TG analysis the thermal decomposition of the complexes occurs by the same mechanism similar to that of the free ligands. In all cases it starts with evolution of molecular nitrogen from the tetrazole ligand which is accompanied by an exothermic effect." @default.
- W2562022035 created "2017-01-06" @default.
- W2562022035 creator A5007037773 @default.
- W2562022035 creator A5015265771 @default.
- W2562022035 creator A5025198736 @default.
- W2562022035 creator A5052679705 @default.
- W2562022035 date "2017-03-01" @default.
- W2562022035 modified "2023-10-18" @default.
- W2562022035 title "Novel water soluble palladium(II) complexes featuring tetrazolylacetic acids and their esters" @default.
- W2562022035 cites W1969360633 @default.
- W2562022035 cites W1970251951 @default.
- W2562022035 cites W1975511395 @default.
- W2562022035 cites W1983828807 @default.
- W2562022035 cites W1990060488 @default.
- W2562022035 cites W2000678326 @default.
- W2562022035 cites W2021035528 @default.
- W2562022035 cites W2049505581 @default.
- W2562022035 cites W2053227378 @default.
- W2562022035 cites W2054327314 @default.
- W2562022035 cites W2059205366 @default.
- W2562022035 cites W2059931977 @default.
- W2562022035 cites W2062865385 @default.
- W2562022035 cites W2066105236 @default.
- W2562022035 cites W2071926746 @default.
- W2562022035 cites W2079150402 @default.
- W2562022035 cites W2090858808 @default.
- W2562022035 cites W2117744900 @default.
- W2562022035 cites W2124966624 @default.
- W2562022035 cites W2131350133 @default.
- W2562022035 cites W2154852246 @default.
- W2562022035 cites W2157315032 @default.
- W2562022035 cites W2160891250 @default.
- W2562022035 cites W2165528549 @default.
- W2562022035 cites W2167432679 @default.
- W2562022035 cites W2170809000 @default.
- W2562022035 cites W2316195170 @default.
- W2562022035 cites W2317258252 @default.
- W2562022035 cites W2518082217 @default.
- W2562022035 cites W2519864734 @default.
- W2562022035 cites W2949398738 @default.
- W2562022035 cites W4242145768 @default.
- W2562022035 cites W4244257404 @default.
- W2562022035 doi "https://doi.org/10.1016/j.poly.2016.12.032" @default.
- W2562022035 hasPublicationYear "2017" @default.
- W2562022035 type Work @default.
- W2562022035 sameAs 2562022035 @default.
- W2562022035 citedByCount "12" @default.
- W2562022035 countsByYear W25620220352018 @default.
- W2562022035 countsByYear W25620220352019 @default.
- W2562022035 countsByYear W25620220352020 @default.
- W2562022035 countsByYear W25620220352021 @default.
- W2562022035 countsByYear W25620220352022 @default.
- W2562022035 crossrefType "journal-article" @default.
- W2562022035 hasAuthorship W2562022035A5007037773 @default.
- W2562022035 hasAuthorship W2562022035A5015265771 @default.
- W2562022035 hasAuthorship W2562022035A5025198736 @default.
- W2562022035 hasAuthorship W2562022035A5052679705 @default.
- W2562022035 hasConcept C161790260 @default.
- W2562022035 hasConcept C178790620 @default.
- W2562022035 hasConcept C185592680 @default.
- W2562022035 hasConcept C188027245 @default.
- W2562022035 hasConcept C21951064 @default.
- W2562022035 hasConcept C3020651653 @default.
- W2562022035 hasConcept C502130503 @default.
- W2562022035 hasConceptScore W2562022035C161790260 @default.
- W2562022035 hasConceptScore W2562022035C178790620 @default.
- W2562022035 hasConceptScore W2562022035C185592680 @default.
- W2562022035 hasConceptScore W2562022035C188027245 @default.
- W2562022035 hasConceptScore W2562022035C21951064 @default.
- W2562022035 hasConceptScore W2562022035C3020651653 @default.
- W2562022035 hasConceptScore W2562022035C502130503 @default.
- W2562022035 hasFunder F4320321079 @default.
- W2562022035 hasFunder F4320322515 @default.
- W2562022035 hasLocation W25620220351 @default.
- W2562022035 hasOpenAccess W2562022035 @default.
- W2562022035 hasPrimaryLocation W25620220351 @default.
- W2562022035 hasRelatedWork W1976351082 @default.
- W2562022035 hasRelatedWork W2022246659 @default.
- W2562022035 hasRelatedWork W2035441315 @default.
- W2562022035 hasRelatedWork W2046361778 @default.
- W2562022035 hasRelatedWork W2119537222 @default.
- W2562022035 hasRelatedWork W2316215216 @default.
- W2562022035 hasRelatedWork W2346010529 @default.
- W2562022035 hasRelatedWork W2953087783 @default.
- W2562022035 hasRelatedWork W4238783471 @default.
- W2562022035 hasRelatedWork W4285223579 @default.
- W2562022035 hasVolume "124" @default.
- W2562022035 isParatext "false" @default.
- W2562022035 isRetracted "false" @default.
- W2562022035 magId "2562022035" @default.
- W2562022035 workType "article" @default.