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- W2562137789 abstract "A facile synthesis of various spirofluorenylpiperidin-4-ones has been achieved in good yields from fluorenone N-aryl nitrones and methylenecyclopropanes. This method involved an initial cycloaddition to form a 5-spirocyclopropane-isoxazoline, which underwent a highly selective 1,3-rearrangement to give the desired product. The stereochemistry of the spirofluorenylpiperidin-4-one could be controlled by the cycloaddition and sequential rearrangement strategy. Furthermore, the spirofluorenylpiperidin-4-ones could be not only prepared in one-pot procedure but also converted to useful scaffolds by reduction or oxidation conditions." @default.
- W2562137789 created "2017-01-06" @default.
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- W2562137789 date "2016-12-27" @default.
- W2562137789 modified "2023-10-16" @default.
- W2562137789 title "Cycloaddition of Fluorenone <i>N</i>-Aryl Nitrones with Methylenecyclopropanes and Sequential 1,3-Rearrangement: An Entry to Synthesis of Spirofluorenylpiperidin-4-ones" @default.
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- W2562137789 doi "https://doi.org/10.1021/acs.joc.6b02544" @default.
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