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- W2562270443 abstract "The preparation of all possible stereoisomers of a given chiral molecule bearing multiple stereocenters by a simple and unified method is a significant challenge in asymmetric catalysis. We report stereodivergent allylic substitutions with aryl acetic acid esters catalyzed synergistically by a metallacyclic iridium complex and benzotetramisole. Through permutations of the enantiomers of the two chiral catalysts, all four stereoisomers of the products bearing two adjacent stereocenters are accessible with high diastereoselectivity and enantioselectivity. The resulting chiral activated ester products can be converted readily to enantioenriched amides, unactivated esters, and carboxylic acids in a one-pot manner." @default.
- W2562270443 created "2017-01-06" @default.
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- W2562270443 date "2016-12-22" @default.
- W2562270443 modified "2023-10-04" @default.
- W2562270443 title "Stereodivergent Allylic Substitutions with Aryl Acetic Acid Esters by Synergistic Iridium and Lewis Base Catalysis" @default.
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- W2562270443 doi "https://doi.org/10.1021/jacs.6b11692" @default.
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