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• W2562303403 abstract "Novel, highly fluorescent cadmium telluride quantum dots conjugated with thymine and stabilized with thioglycolic acid were obtained and characterized. Successful formation of the conjugate was confirmed by elemental analysis, and UV-vis, fluorescence and Fourier transform infrared spectroscopies. Crystal structure and composition of the conjugates were characterized with xray diffraction and x-ray photoelectron spectroscopy. The size of the conjugates was 4-6 nm as demonstrated using atomic force microscopy and high resolution transmission electron microscopy imaging. The plasmon resonance fluorescence band at 540 nm on excitation at 351 nm was observed for these nanoparticles. The intensity of this band increased with the increase in the amount of conjugated thymine with no shift in its position. Based on the fluorescence measurements it was found that the CdTe-thymine conjugate interacted efficiently and selectively not only with adenine, a nucleobase complementary to thymine, but also with adenine-containing modified nucleosides, i.e., 5'-deoxy-5'-(methylthio)adenosine and 2'-O-methyladenosine, the urinary tumor markers which allow monitoring of the disease progression. To the best of our knowledge, as yet, there have been no studies presented in literature on that type of the interaction with CdTe-thymine conjugates. Therefore, the system presented can be considered as a working component of a selective adenine/adenosine biosensor with potential application in cancer diagnosis." @default.
• W2562303403 created "2017-01-06" @default.
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• W2562303403 date "2016-12-15" @default.
• W2562303403 modified "2023-10-16" @default.
• W2562303403 title "Novel fluorescent CdTe quantum dot–thymine conjugate—synthesis, properties and possible application" @default.
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• W2562303403 doi "https://doi.org/10.1088/1361-6528/28/4/045701" @default.
• W2562303403 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27977416" @default.
• W2562303403 hasPublicationYear "2016" @default.
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