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• W2562360748 abstract "In recent years, interest in ferrate(VI) has increased significantly. Ferrate is a strong, non-toxic oxidant with almost no harmful by products. It is potentially an environmental friendly cleaner for both waste water and drinking water treatment. Therefore, effective means of the preparation of ferrate become a challenging task for several research groups all over the world. Several methods have been developed to produce ferrate. Among them, electrochemical mean of the synthesis of ferrate is considered as a “green” method because no harmful and expensive chemicals are usually used to oxidize Fe(0) to Fe(VI). One of the most important tasks is the elucidation of the reaction mechanism of the ferrate production. Conditions for the large scale electrochemical preparation of ferrate in low temperature molten media can be tuned according to the individual steps of the reaction mechanism. The influence of parameters such as the temperature and the composition of reaction mixture, anode material, and current density on the mechanism of ferrate preparation during transpassive electrochemical dissolution of iron based electrodes are addressed. Two electrochemical methods, cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) were used to characterize this process. The number of exchanged electrons during transpassive iron dissolution was also determined and the reaction mechanism was proposed." @default.
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• W2562360748 date "2016-01-01" @default.
• W2562360748 modified "2023-09-26" @default.
• W2562360748 title "Electrochemical Ferrates(VI) Preparation and Wastewater Treatment" @default.
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• W2562360748 doi "https://doi.org/10.1021/bk-2016-1238.ch008" @default.
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