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- W2562504034 abstract "Interfacial phenomena play an important role in pyrometallurgical processes and knowledge of them and of physical properties involved is necessary for understanding the mechanisms and the kinetics of such reactions. A large number of measurements, performed at Irsid under equilibrium conditions, are presented in this review. Several experimental techniques were used and more particularly: – Sessile drop method for measurement of liquid metals surface tension and contact angle liquid metal/solid oxide; – measurement of the contact angle between a liquid slag drop and its liquid metal substrate from which the interfacial tension can be derived; – direct determination of the interfacial tension from X‐ray pictures of metal drops immersed in the slag. The systems studied consisted, for the metal phase, of binary and ternary Fe alloys containing C, Mn, Si, O, S and, for the slag phase, binary and ternary mixtures made from CaO, SiO 2 , Al 2 O 3 , MnO, iron oxides, CaF 2 and Na 2 O. A strong effect of O and S potentials was observed. For non‐equilibrium conditions, however, the dynamic interfacial tension between liquid metal and slag decreases sharply when an intense mass transfer occurs through the interface. The potential consideration of interfacial turbulence phenomena (Marangoni effect) in metallurgical reactions is also discussed." @default.
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- W2562504034 date "1988-06-01" @default.
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- W2562504034 title "Interfacial phenomena and mass transfer in extractive metallurgy" @default.
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- W2562504034 doi "https://doi.org/10.1002/srin.198801639" @default.
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