Matches in SemOpenAlex for { <https://semopenalex.org/work/W2562963669> ?p ?o ?g. }
Showing items 1 to 76 of
76
with 100 items per page.
- W2562963669 endingPage "279" @default.
- W2562963669 startingPage "275" @default.
- W2562963669 abstract "A regio- and chemoselective C–H deprotonative strategy toward arynes is described that employs a hypervalent iodine leaving group. The unsymmetrical aryl(mesityl)iodonium salts used as aryne precursors are readily synthesized from commercially available aryl iodide and arylboronic acid building blocks. The bases LiHMDS and NaO<i>t</i>-Bu engage the diaryliodonium salts in a deprotonation event at an aromatic C–H bond and the transient arynes react in cycloaddition reactions with furan and benzyl azide or nucleophilic addition reaction with alicyclic amines. The auxiliary component of aryl(auxiliary)iodonium salts can be sterically tuned to influence the regioselectivity of the C–H deprotonation event for <i>meta</i>-substituted aryl groups. 1 Introduction 2 Iodonium Salts as Aryne Precursors 3 Reaction Discovery and Optimization 4 Reaction Scope 5 Auxiliary-Controlled Regioselective Deprotonation 6 Beyond Cycloaddition with Furan 7 Conclusions and Outlook" @default.
- W2562963669 created "2017-01-06" @default.
- W2562963669 creator A5076284444 @default.
- W2562963669 date "2016-12-22" @default.
- W2562963669 modified "2023-10-12" @default.
- W2562963669 title "Unsymmetrical Diaryliodonium Salts as Aryne Synthons: Renaissance of a C–H Deprotonative Approach to Arynes" @default.
- W2562963669 doi "https://doi.org/10.1055/s-0036-1588683" @default.
- W2562963669 hasPublicationYear "2016" @default.
- W2562963669 type Work @default.
- W2562963669 sameAs 2562963669 @default.
- W2562963669 citedByCount "25" @default.
- W2562963669 countsByYear W25629636692017 @default.
- W2562963669 countsByYear W25629636692018 @default.
- W2562963669 countsByYear W25629636692019 @default.
- W2562963669 countsByYear W25629636692021 @default.
- W2562963669 countsByYear W25629636692022 @default.
- W2562963669 countsByYear W25629636692023 @default.
- W2562963669 crossrefType "journal-article" @default.
- W2562963669 hasAuthorship W2562963669A5076284444 @default.
- W2562963669 hasConcept C118629725 @default.
- W2562963669 hasConcept C145148216 @default.
- W2562963669 hasConcept C155647269 @default.
- W2562963669 hasConcept C161790260 @default.
- W2562963669 hasConcept C171811041 @default.
- W2562963669 hasConcept C178790620 @default.
- W2562963669 hasConcept C178907741 @default.
- W2562963669 hasConcept C185592680 @default.
- W2562963669 hasConcept C20774148 @default.
- W2562963669 hasConcept C21951064 @default.
- W2562963669 hasConcept C2777650178 @default.
- W2562963669 hasConcept C2778659115 @default.
- W2562963669 hasConcept C2779664164 @default.
- W2562963669 hasConcept C2780263894 @default.
- W2562963669 hasConcept C2780997848 @default.
- W2562963669 hasConcept C2781076698 @default.
- W2562963669 hasConcept C40869318 @default.
- W2562963669 hasConcept C59759590 @default.
- W2562963669 hasConceptScore W2562963669C118629725 @default.
- W2562963669 hasConceptScore W2562963669C145148216 @default.
- W2562963669 hasConceptScore W2562963669C155647269 @default.
- W2562963669 hasConceptScore W2562963669C161790260 @default.
- W2562963669 hasConceptScore W2562963669C171811041 @default.
- W2562963669 hasConceptScore W2562963669C178790620 @default.
- W2562963669 hasConceptScore W2562963669C178907741 @default.
- W2562963669 hasConceptScore W2562963669C185592680 @default.
- W2562963669 hasConceptScore W2562963669C20774148 @default.
- W2562963669 hasConceptScore W2562963669C21951064 @default.
- W2562963669 hasConceptScore W2562963669C2777650178 @default.
- W2562963669 hasConceptScore W2562963669C2778659115 @default.
- W2562963669 hasConceptScore W2562963669C2779664164 @default.
- W2562963669 hasConceptScore W2562963669C2780263894 @default.
- W2562963669 hasConceptScore W2562963669C2780997848 @default.
- W2562963669 hasConceptScore W2562963669C2781076698 @default.
- W2562963669 hasConceptScore W2562963669C40869318 @default.
- W2562963669 hasConceptScore W2562963669C59759590 @default.
- W2562963669 hasIssue "03" @default.
- W2562963669 hasLocation W25629636691 @default.
- W2562963669 hasOpenAccess W2562963669 @default.
- W2562963669 hasPrimaryLocation W25629636691 @default.
- W2562963669 hasRelatedWork W2035848999 @default.
- W2562963669 hasRelatedWork W2037999593 @default.
- W2562963669 hasRelatedWork W2042322078 @default.
- W2562963669 hasRelatedWork W2059777404 @default.
- W2562963669 hasRelatedWork W2097299541 @default.
- W2562963669 hasRelatedWork W2204260480 @default.
- W2562963669 hasRelatedWork W2322072612 @default.
- W2562963669 hasRelatedWork W2949637801 @default.
- W2562963669 hasRelatedWork W2950543267 @default.
- W2562963669 hasRelatedWork W4200324824 @default.
- W2562963669 hasVolume "28" @default.
- W2562963669 isParatext "false" @default.
- W2562963669 isRetracted "false" @default.
- W2562963669 magId "2562963669" @default.
- W2562963669 workType "article" @default.