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- W2563006061 abstract "Abstract Linearly polarized absorption spectra and magnetic circular dichroism (MCD) spectra of ErAl3(BO3)4 single crystal were measured in the range of 10000–27000 cm−1 at 90 K. The Stark components of the ground and excited multiplets of Er3+ ion were identified in terms of the irreducible representations, basing on the linearly polarized absorption spectra. MCD spectra permitted us to measure the Zeeman splitting of some transitions and so to determine changes of the Lande factors along the C3 axis during these transitions. Additionally, the MCD spectra permitted us to identify some states in the | J , ± M J 〉 function approximation. In particular, it was shown that the ground state of the Er3+ ion in this approximation has MJ = ± 13/2 that corresponds to magnetic moment m = ±7.8 μB. Very intensive f-f vibronic transitions, corresponding to electron transitions from the upper components of the ground multiplet, were revealed. Energies of the local vibrations in a number of the excited states were found." @default.
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- W2563006061 date "2017-03-01" @default.
- W2563006061 modified "2023-09-25" @default.
- W2563006061 title "Optical and magneto-optical spectra and electron structure of ErAl 3 (BO 3 ) 4 single crystal" @default.
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- W2563006061 doi "https://doi.org/10.1016/j.jallcom.2016.12.200" @default.
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