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- W2563048361 abstract "Abstract Magnetoelectric multiferroics are very promising materials because of their practical applications and fundamental interests. The most widely studied magnetoelectric oxides are ABO 3 perovskites. In the paper structural properties of BiFeO 3 and Pb(Fe 0.5 Nb 0.5 )O 3 solid solution are described. The material crystallizes in rhombohedral R3c crystal structure which parameters are presented. Mossbauer spectroscopy was used to study local changes in an iron environment due to Fe/Nb substitution and hyperfine interaction parameters of different local surroundings of iron atoms are presented. The random distribution of B-site sublattice cations was confirmed. Ab initio calculations of the studied solid solution were conducted and theoretical crystal structure parameters were compared with the experimental data. The theoretical magnetic and electric properties are discussed. The local iron magnetic moments were estimated and their dependence on the local surrounding changes is shown. The calculated electrons densities and Bader's topological analysis were used to describe chemical bonding properties." @default.
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- W2563048361 date "2017-04-01" @default.
- W2563048361 modified "2023-10-17" @default.
- W2563048361 title "Structural properties of multiferroic 0.5BiFeO3–0.5Pb(Fe0.5Nb0.5)O3 solid solution" @default.
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- W2563048361 doi "https://doi.org/10.1016/j.jeurceramsoc.2016.11.029" @default.
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