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- W2563313105 abstract "Using in situ X-ray photoelectron spectroscopy, reflection high-energy electron diffraction, and density functional theory, we analyzed the surface core level shifts and surface structure during the initial growth of ABO3 perovskites on Ge (001) by atomic layer deposition, where A = Ba, Sr and B = Ti, Hf, Zr. We find that the initial dosing of the barium- or strontium-bis(triisopropylcyclopentadienyl) precursors on a clean Ge surface produces a surface phase that has the same chemical and structural properties as the 0.5-monolayer Ba Zintl layer formed when depositing Ba by molecular beam epitaxy. Similar binding energy shifts are found for Ba, Sr, and Ge when using either chemical or elemental metal sources. The observed germanium surface core level shifts are consistent with the flattening of the initially tilted Ge surface dimers using both molecular and atomic metal sources. Similar binding energy shifts and changes in dimer tilting with alkaline earth metal adsorption are found with density functional theory calculations. High angle angular dark field scanning transmission microscopy images of BaTiO3, SrZrO3, SrHfO3, and SrHf0.55Ti0.45O3 reveal the location of the Ba (or Sr) atomic columns between the Ge dimers. The results imply that the organic ligands dissociate from the precursor after precursor adsorption on the Ge surface, producing the same Zintl template critical for perovskite growth on Group IV semiconductors during molecular beam epitaxy." @default.
- W2563313105 created "2017-01-06" @default.
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- W2563313105 date "2016-12-19" @default.
- W2563313105 modified "2023-10-18" @default.
- W2563313105 title "Zintl layer formation during perovskite atomic layer deposition on Ge (001)" @default.
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- W2563313105 cites W1967490401 @default.
- W2563313105 cites W1967512017 @default.
- W2563313105 cites W1970127494 @default.
- W2563313105 cites W1979544533 @default.
- W2563313105 cites W1979654866 @default.
- W2563313105 cites W1979822943 @default.
- W2563313105 cites W1981368803 @default.
- W2563313105 cites W1984781904 @default.
- W2563313105 cites W1988877056 @default.
- W2563313105 cites W1993157042 @default.
- W2563313105 cites W1994859465 @default.
- W2563313105 cites W1995209704 @default.
- W2563313105 cites W1997744870 @default.
- W2563313105 cites W1998108281 @default.
- W2563313105 cites W2000005525 @default.
- W2563313105 cites W2006626217 @default.
- W2563313105 cites W2006964883 @default.
- W2563313105 cites W2007395042 @default.
- W2563313105 cites W2010468068 @default.
- W2563313105 cites W2010741836 @default.
- W2563313105 cites W2011965890 @default.
- W2563313105 cites W2017278537 @default.
- W2563313105 cites W2017529137 @default.
- W2563313105 cites W2021404872 @default.
- W2563313105 cites W2023289066 @default.
- W2563313105 cites W2025626594 @default.
- W2563313105 cites W2033768059 @default.
- W2563313105 cites W2036113194 @default.
- W2563313105 cites W2039260506 @default.
- W2563313105 cites W2044013678 @default.
- W2563313105 cites W2045480406 @default.
- W2563313105 cites W2047552169 @default.
- W2563313105 cites W2048726969 @default.
- W2563313105 cites W2049101255 @default.
- W2563313105 cites W2052637367 @default.
- W2563313105 cites W2053930414 @default.
- W2563313105 cites W2054084603 @default.
- W2563313105 cites W2054704030 @default.
- W2563313105 cites W2055432884 @default.
- W2563313105 cites W2056089779 @default.
- W2563313105 cites W2058964537 @default.
- W2563313105 cites W2059930388 @default.
- W2563313105 cites W2062486407 @default.
- W2563313105 cites W2064986213 @default.
- W2563313105 cites W2066038783 @default.
- W2563313105 cites W2067563576 @default.
- W2563313105 cites W2072451721 @default.
- W2563313105 cites W2079105963 @default.
- W2563313105 cites W2081546967 @default.
- W2563313105 cites W2082488525 @default.
- W2563313105 cites W2083222334 @default.
- W2563313105 cites W2087698390 @default.
- W2563313105 cites W2089332077 @default.
- W2563313105 cites W2103426813 @default.
- W2563313105 cites W2106603672 @default.
- W2563313105 cites W2118952051 @default.
- W2563313105 cites W2122913038 @default.
- W2563313105 cites W2125279981 @default.
- W2563313105 cites W2125580171 @default.
- W2563313105 cites W2165429900 @default.
- W2563313105 cites W2320552558 @default.
- W2563313105 cites W2334312907 @default.
- W2563313105 cites W2335380808 @default.
- W2563313105 cites W2494314550 @default.
- W2563313105 cites W2494889450 @default.
- W2563313105 cites W2519185031 @default.
- W2563313105 cites W2963251738 @default.
- W2563313105 cites W2993783326 @default.
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- W2563313105 doi "https://doi.org/10.1063/1.4972071" @default.
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- W2563313105 hasPublicationYear "2016" @default.
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