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- W2563384685 abstract "Abstract While chemoselectivities in Pd 0 ‐catalyzed coupling reactions are frequently non‐intuitive and a result of a complex interplay of ligand/catalyst, substrate, and reaction conditions, we herein report a general method based on Pd I that allows for an a priori predictable chemoselective C −C coupling at C−Br in preference to C−OTf and C−Cl bonds, regardless of the electronic or steric bias of the substrate. The C−C bond formations are extremely rapid (<5 min at RT) and are catalyzed by an air‐ and moisture‐stable Pd I dimer under open‐flask conditions." @default.
- W2563384685 created "2017-01-06" @default.
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- W2563384685 date "2016-12-29" @default.
- W2563384685 modified "2023-10-17" @default.
- W2563384685 title "Rapid Room‐Temperature, Chemoselective C−C Coupling of Poly(pseudo)halogenated Arenes Enabled by Palladium(I) Catalysis in Air" @default.
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- W2563384685 doi "https://doi.org/10.1002/anie.201609635" @default.
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