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- W2563511032 abstract "Abstract The crystal structure of Cs 2 CuP 2 O 7 [monoclinic, Cc , a =7.460(6), b =12.973(10), c =9.980(8) Å, β=111.95(2)°, V =895.8(12) Å 3 ] prepared by solid-state reactions is based upon open framework formed by corner sharing between CuO 4 distorted squares and P 2 O 7 groups. The framework is porous and has a very low framework density of 13.4 Cu+P atoms per 1 nm 3 . Cs + cations reside in large framework cavities. The heteropolyhedral network in the title compound is based upon three-dimensional (3;4)-connected net that has a three-membered CuP 2 ring as its elementary unit. In terms of reticular chemistry, this net should be considered as an augmented diamond ( dia ) net. The Cu–P net can be obtained from the latter by the replacement of its nodes by the CuP 2 triangles. This replacement is strongly non-centrosymmetric, since all CuP 2 triangles are oriented along the same direction, which provides a crystal chemical explanation for the absence of a symmetry centre in the structure. Cs 2 CuP 2 O 7 is the first compound in the A 2 CuP 2 O 7 family (A=alkaline metal), which is based upon three-dimensional copper pyrophosphate framework." @default.
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- W2563511032 date "2015-10-31" @default.
- W2563511032 modified "2023-09-27" @default.
- W2563511032 title "Cs<sub>2</sub>CuP<sub>2</sub>O<sub>7</sub>, a novel low-density open-framework structure based upon an augmented diamond net" @default.
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- W2563511032 doi "https://doi.org/10.1515/zkri-2015-1894" @default.
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