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- W2563663854 abstract "We report a method to construct chiral tetraorganosilicons by tandem silacyclobutane (SCB) desymmetrization-dehydrogenative silylations. A wide array of dibenzosiloles with stereogenic quaternary silicon centers were obtained in good yields and enantioselectivities up to 93 % ee. Chiral TMS-segphos was found to be a superior ligand in terms of reactivity and enantioselectivity." @default.
- W2563663854 created "2017-01-06" @default.
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- W2563663854 date "2016-12-19" @default.
- W2563663854 modified "2023-10-03" @default.
- W2563663854 title "Construction of Chiral Tetraorganosilicons by Tandem Desymmetrization of Silacyclobutanes/Intermolecular Dehydrogenative Silylation" @default.
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- W2563663854 doi "https://doi.org/10.1002/anie.201609022" @default.
- W2563663854 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27990736" @default.
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