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- W2563856605 abstract "The thermal decomposition of Mn11, Fe111, Cu ΙΙ , Ni ΙΙ and Cu ΙΙ chelates of 3-(3-furan-2-yl-acryloyl)-4-hydroxy-6-methyl-pyran-2-one was studied by TG-DTA and X-ray powder diffraction methods. The thermal stability of the complexes was studied using thermogravimetry and the decomposition schemes of the complexes were given. The mechanism of the decomposition has been established from TG data. The kinetic parameters i.e. n (order of reaction), E (energy of activation), Z (pre-exponential factor), AS (entropy change) and AG (free energy change) were calculated from the TG curve using mechanistic (Sestak-Berggren and Satava) and non-mechanistic (Coats-Redfern, MacCallum-Tanner and Horowitz-Metzger) integral equations." @default.
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- W2563856605 date "2008-08-31" @default.
- W2563856605 modified "2023-10-14" @default.
- W2563856605 title "A mechanistic and non-mechanistic approach on the solid state thermal decomposition of transition metal complexes of 3-(3-furan-2-yl-acryloyl)- 4-hydroxy-6-methyl-pyran-2-one" @default.
- W2563856605 doi "https://doi.org/10.5281/zenodo.5819437" @default.
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