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- W2563934341 endingPage "1157" @default.
- W2563934341 startingPage "1152" @default.
- W2563934341 abstract "Abstract Supramolecular capsules were assembled by neutral halogen bonding (XB) and studied in the solid state, in solution, and in the gas phase. The geometry of the highly organized capsules is shown by an X‐ray crystal structure which features the assembly of two XB hemispheres, geometrically rigidified by H‐bonding to eight MeOH molecules and encapsulation of two benzene guests. To enhance capsular association strength, tuning the XB donor is more efficient than tuning the XB acceptor, due to desolvation penalties in protic solvents, as shown for a tetraquinuclidine XB acceptor hemisphere. With a tetra(iodoethynyl) XB donor and a tetralutidine XB acceptor, the association in deuterated benzene/acetone/methanol 70:30:1 at 283 K reaches K a =(2.11±0.39)×10 5 m −1 (Δ G =−6.9±0.1 kcal mol −1 ). The stability of the XB capsules in the gas phase was confirmed by electrospray ionization mass spectrometry (ESI‐MS). A new guest binding site was uncovered within the elongated iodoethynyl capsule." @default.
- W2563934341 created "2017-01-06" @default.
- W2563934341 creator A5005244793 @default.
- W2563934341 creator A5009896896 @default.
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- W2563934341 creator A5029264864 @default.
- W2563934341 creator A5064252894 @default.
- W2563934341 creator A5073517394 @default.
- W2563934341 date "2016-12-21" @default.
- W2563934341 modified "2023-09-25" @default.
- W2563934341 title "Halogen-Bonded Supramolecular Capsules in the Solid State, in Solution, and in the Gas Phase" @default.
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