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- W2564223845 abstract "The conversion of synthetic porphyrins to derivatives that contain a nonpyrrolic building block is an appealing method to generate porphyrinoids with functional groups at their periphery for sensing applications or chromophores with fine-tuned electronic properties for a number of technical and biomedical applications. Baeyer–Villiger oxidations are potentially suited to generate such pyrrole-expanded porphyrinoids from known octaethyloxochlorin. However, the application of different Baeyer–Villiger-oxidation conditions to this ketone merely led to the formation of novel and known compounds, such as porphyrinic meso-OH and N-oxide derivatives. This work demonstrates how the extraordinary structural stability of the porphyrin macrocycle redirects the reactivity patterns of classic ring-expansion reactions, which outlines some limits of the methods to convert a pyrrole in porphyrins into a nonpyrrolic building block." @default.
- W2564223845 created "2017-01-06" @default.
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- W2564223845 date "2017-01-24" @default.
- W2564223845 modified "2023-09-28" @default.
- W2564223845 title "Surprising Outcomes of Classic Ring‐Expansion Conditions Applied to Octaethyloxochlorin, 1. Baeyer–Villiger‐Oxidation Conditions" @default.
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- W2564223845 doi "https://doi.org/10.1002/ejoc.201601422" @default.
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