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• W2564291026 abstract "Compounds which undergo excited-state intramolecular proton-transfer (ESIPT) have been widely applied in biophysical investigations as fluorescence sensors enabling several analytical signals. Low fluorescence quantum yields in protic media seem to be, however, their main drawback. In this study, we investigated spectral features of 4′-N,N-dimethylaminoflavone derivatives containing hydroxyl groups at positions 3 and/or 7 in protic solid media—poly(vinyl alcohol) (PVA) films at various concentrations and under conditions of fluorescence intensity enhancement by plasmonic resonance. Our experimental findings indicate that, due to ESIPT and susceptibility of the investigated compounds to the polarity and hydrogen-bonding ability of the medium, various tautomeric species localized in different domains of PVA can be distinguished in the ground and electronically excited states, which determines multiple spectral parameters of such materials. According to the evaluated rate constants, relaxation and aggregatio..." @default.
• W2564291026 created "2017-01-06" @default.
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• W2564291026 date "2017-01-03" @default.
• W2564291026 modified "2023-10-17" @default.
• W2564291026 title "Spectral Features and Excited-State Transformations of Hydroxy Derivatives of 4′-<i>N</i>,<i>N</i>-Dimethylaminoflavone in PVA Films and on Plasmonic Platforms" @default.
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• W2564291026 doi "https://doi.org/10.1021/acs.jpcc.6b07386" @default.
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