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W2564316964 abstract "Sodium-copper hexacyanoferrate-modified magnetic nanoparticles were fabricated for the highly efficient removal of radioactive cesium followed by the rapid magnetic separation of the absorbent from water. The Fe3O4 nanoparticles, synthesized using a hydrothermal method, were coated with polyethyleneimine to immobilize Cu ions through metal coordination to amine groups in the PEI. Sodium-copper hexacyanoferrate (NaCuHCF) was subsequently formed on the surfaces of the magnetic nanoparticles as Cu ions coordinated the hexacyanoferrate ions. The resulting NaCuHCF-modified magnetic nanoparticles displayed an excellent saturation magnetization value (45.2 emu/g). Batch experiments revealed that cesium adsorption equilibrium was rapidly achieved within 10 min, and the maximum adsorption capacity of the adsorbent was 125 mg/g. The adsorption kinetics and isotherms fit well to a pseudo-second order model and Langmuir isotherm, respectively. The NaCuHCF-MNPs provided a high removal efficiency exceeding 99.428% of the radioactive cesium present. The adsorbent selectively adsorbed 137Cs, even in the presence of competing cations." @default.
W2564316964 created "2017-01-06" @default.
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W2564316964 date "2017-03-01" @default.
W2564316964 modified "2023-10-10" @default.
W2564316964 title "Highly efficient removal of radioactive cesium by sodium-copper hexacyanoferrate-modified magnetic nanoparticles" @default.
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W2564316964 doi "https://doi.org/10.1016/j.colsurfa.2016.12.052" @default.
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