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- W256454080 abstract "Here, we report a study of two isoelectronic Ir(I) complexes supported by different carboranyl phosphines, bearing either o-carborane or carba-closo-dodecaborate ligand substituents. The neutral Ir(I) complex containing the o-carboranyl phosphine ligand is not isolable and undergoes spontaneous B–H cyclometalation to afford an Ir(III) hydride. In contrast, the anionic Ir(I) complex supported by a phosphine with a carba-closo-dodecaborate ligand R-group is stable towards B–H activation. This divergent reactivity has important implications for the design of carborane containing ligands for catalysis. Both compounds are fully characterized by multinuclear NMR spectroscopy, HRMS spectrometry, and single crystal x-ray diffraction studies." @default.
- W256454080 created "2016-06-24" @default.
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- W256454080 date "2015-12-01" @default.
- W256454080 modified "2023-10-18" @default.
- W256454080 title "Resisting B–H oxidative addition: The divergent reactivity of the o-carborane and carba-closo-dodecaborate ligand substituents" @default.
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- W256454080 doi "https://doi.org/10.1016/j.jorganchem.2015.05.008" @default.
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