Matches in SemOpenAlex for { <https://semopenalex.org/work/W2564569610> ?p ?o ?g. }
Showing items 1 to 77 of
77
with 100 items per page.
- W2564569610 abstract "The nitrone mediated polymerization of methyl methacrylate (MMA) via the enhanced (termination) spin capturing polymerization (ESCP) process is made possible via the addition of small amounts of styrene (between 5 and 10 vol.%) to the reaction mixture. Efficient control over the molecular weight between 7000 and 57,000 g mol-1 (at 60 °C) yields macromolecules that feature a mid-chain alkoxyamine functionality and are rich in methyl methacrylate. The collated kinetic and molecular weight data allow for a deduction of the spin capturing constant, CSC, in the range between 0.15 and 0.30. During the ESCP process, the number average molecular weight, Mn, of the formed mid-chain functional polymer is constant up to high monomer to polymer conversions (i.e. 80%). The high degree of alkoxyamine mid-chain functionality present in the generated polymeric material is evidenced via a subsequent nitroxide-mediated polymerization process employing the formed ESCP polymer, indicating a chain extension from 37,700 to 118,000 g mol-1 with a concomitant reduction in polydispersity (from 2.3 to 1.5). © 2010 Elsevier Ltd." @default.
- W2564569610 created "2017-01-06" @default.
- W2564569610 creator A5004482996 @default.
- W2564569610 creator A5009049591 @default.
- W2564569610 creator A5010160881 @default.
- W2564569610 creator A5021541475 @default.
- W2564569610 date "2010-01-01" @default.
- W2564569610 modified "2023-09-28" @default.
- W2564569610 title "Control of methyl methacrylate radical polymerization via Enhanced Spin Capturing Polymerization (ESCP)" @default.
- W2564569610 hasPublicationYear "2010" @default.
- W2564569610 type Work @default.
- W2564569610 sameAs 2564569610 @default.
- W2564569610 citedByCount "0" @default.
- W2564569610 crossrefType "journal-article" @default.
- W2564569610 hasAuthorship W2564569610A5004482996 @default.
- W2564569610 hasAuthorship W2564569610A5009049591 @default.
- W2564569610 hasAuthorship W2564569610A5010160881 @default.
- W2564569610 hasAuthorship W2564569610A5021541475 @default.
- W2564569610 hasConcept C111998727 @default.
- W2564569610 hasConcept C11432220 @default.
- W2564569610 hasConcept C121120078 @default.
- W2564569610 hasConcept C132050475 @default.
- W2564569610 hasConcept C158117686 @default.
- W2564569610 hasConcept C166940927 @default.
- W2564569610 hasConcept C16728422 @default.
- W2564569610 hasConcept C169912494 @default.
- W2564569610 hasConcept C178790620 @default.
- W2564569610 hasConcept C185592680 @default.
- W2564569610 hasConcept C188027245 @default.
- W2564569610 hasConcept C192562407 @default.
- W2564569610 hasConcept C2777935641 @default.
- W2564569610 hasConcept C44228677 @default.
- W2564569610 hasConcept C48396125 @default.
- W2564569610 hasConcept C521977710 @default.
- W2564569610 hasConceptScore W2564569610C111998727 @default.
- W2564569610 hasConceptScore W2564569610C11432220 @default.
- W2564569610 hasConceptScore W2564569610C121120078 @default.
- W2564569610 hasConceptScore W2564569610C132050475 @default.
- W2564569610 hasConceptScore W2564569610C158117686 @default.
- W2564569610 hasConceptScore W2564569610C166940927 @default.
- W2564569610 hasConceptScore W2564569610C16728422 @default.
- W2564569610 hasConceptScore W2564569610C169912494 @default.
- W2564569610 hasConceptScore W2564569610C178790620 @default.
- W2564569610 hasConceptScore W2564569610C185592680 @default.
- W2564569610 hasConceptScore W2564569610C188027245 @default.
- W2564569610 hasConceptScore W2564569610C192562407 @default.
- W2564569610 hasConceptScore W2564569610C2777935641 @default.
- W2564569610 hasConceptScore W2564569610C44228677 @default.
- W2564569610 hasConceptScore W2564569610C48396125 @default.
- W2564569610 hasConceptScore W2564569610C521977710 @default.
- W2564569610 hasLocation W25645696101 @default.
- W2564569610 hasOpenAccess W2564569610 @default.
- W2564569610 hasPrimaryLocation W25645696101 @default.
- W2564569610 hasRelatedWork W162488021 @default.
- W2564569610 hasRelatedWork W1971114984 @default.
- W2564569610 hasRelatedWork W1979810682 @default.
- W2564569610 hasRelatedWork W2007257160 @default.
- W2564569610 hasRelatedWork W2024721900 @default.
- W2564569610 hasRelatedWork W2025506102 @default.
- W2564569610 hasRelatedWork W2028849332 @default.
- W2564569610 hasRelatedWork W2064585035 @default.
- W2564569610 hasRelatedWork W2098209506 @default.
- W2564569610 hasRelatedWork W2121303251 @default.
- W2564569610 hasRelatedWork W2124295104 @default.
- W2564569610 hasRelatedWork W2153063738 @default.
- W2564569610 hasRelatedWork W2368968862 @default.
- W2564569610 hasRelatedWork W2486110486 @default.
- W2564569610 hasRelatedWork W2559650148 @default.
- W2564569610 hasRelatedWork W2583949130 @default.
- W2564569610 hasRelatedWork W2749299745 @default.
- W2564569610 hasRelatedWork W2788841577 @default.
- W2564569610 hasRelatedWork W2944646329 @default.
- W2564569610 hasRelatedWork W2990668010 @default.
- W2564569610 isParatext "false" @default.
- W2564569610 isRetracted "false" @default.
- W2564569610 magId "2564569610" @default.
- W2564569610 workType "article" @default.