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- W2565110706 abstract "Abstract This work deals with the recovery of Molybdenum (VI) (Mo) from aqueous solutions carried out by solvent extraction (SX) using the bis(2-ethylhexyl) phosphoric acid (D2EHPA) diluted in kerosene and compared with two hydrophobic room temperature ionic liquids (RTILs) as potential replacements of the kerosene. These RTILs were 1-butyl-3-methyl-imidazolium bis (trifluoromethylsulfonyl) imide, [bmim][Tf2N], and 1-octyl-3-methyl-imidazolium bis(trifluoromethylsulfonyl)imide [omim][Tf2N], because of its excellent properties such as negligible vapor pressure, high hydrophobicity and better extraction capacity than conventional organic diluents. Experimental results indicate that the extraction stoichiometry agrees with a cation exchange with formation of a neutral complex. The use of the selected RTILs as diluents involves higher extraction percentages for the whole measured range of extractant concentration and aqueous-organic ratios, reducing four times the required volume of diluent compared to the experiments carried out with kerosene. Furthermore, the proposed extraction medium offers excellent stripping capacity when a solution of ammonium carbonate is used as a stripping phase." @default.
- W2565110706 created "2017-01-06" @default.
- W2565110706 creator A5043725540 @default.
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- W2565110706 date "2017-04-01" @default.
- W2565110706 modified "2023-09-29" @default.
- W2565110706 title "Solvent extraction of molybdenum (VI) from aqueous solution using ionic liquids as diluents" @default.
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- W2565110706 doi "https://doi.org/10.1016/j.seppur.2016.12.045" @default.
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