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- W2565329158 abstract "Abstract The crystal field energy levels (obtained from optical spectra) together with the spin-Hamiltonian parameters g // , g ⊥ and D (obtained from EPR spectra) for 3 d 3 ions Cr 3+ and Mn 4+ at the trigonal octahedral Ga 3+ sites in La 3 Ga 5 SiO 14 crystals are computed from the complete diagonalization (of energy matrix) method based on the two-spin-orbit-parameter model. The model takes into account the contributions due to the spin-orbit parameter of central d n ion (in the traditional crystal field theory) and that of ligand ions via covalence effect. The calculated results are in rational accord with the experimental values. The calculations also imply that the covalence of (MnO 6 ) 8− center in La 3 Ga 5 SiO 14 crystals is stronger than that of (CrO 6 ) 9− center, and the impurity-induced local lattice relaxation for (MnO 6 ) 8− center is larger than that for (CrO 6 ) 9− cluster because of the larger size and charge mismatch for Mn 4+ replacing Ga 3+ in La 3 Ga 5 SiO 14 crystals." @default.
- W2565329158 created "2017-01-06" @default.
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- W2565329158 date "2017-02-01" @default.
- W2565329158 modified "2023-09-24" @default.
- W2565329158 title "Crystal field energy levels, spin-Hamiltonian parameters and local structures for the Cr 3+ and Mn 4+ centers in La 3 Ga 5 SiO 14 crystals" @default.
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- W2565329158 doi "https://doi.org/10.1016/j.optmat.2016.12.033" @default.
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