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- W2565372263 abstract "Semi-dilute solutions of carboxylato telechelic polymers in nonpolar solvents form homogeneous gels. At higher dilutions, the gel turns into a viscous solution or a phase-separated system, depending on the stre.ngth of the ion-pair interactions. The sol-gel transition scales quali tatively as the overlap concentration of the polymer chains. For Mg-carboxylato telechelic polybutadiene in toluene at 25°C, it varies inversely as the square root of the molecu lar weight. The segmental cross-section of the polymer also has a crucial effect on the critical concentration of gela tion. The internal structure of the gel is expected to chan ge into a more compact network when phase-separation and shear-thickening are observed under the influence of swel ling forces and shear flow,respectively." @default.
- W2565372263 created "2017-01-06" @default.
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- W2565372263 date "1987-01-01" @default.
- W2565372263 modified "2023-09-27" @default.
- W2565372263 title "GELATION AND PHASE SEPARATION OF SOLUTIONS OF HALATO TELE CHELIC POLYMERS" @default.
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