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- W2565394229 abstract "High-power sodium-ion batteries (SIBs) with long-term cycling attract increasing attention for large-scale energy storage. However, traditional SIBs toward practical applications still suffer from low rate capability and poor cycle induced by pulverization and amorphorization of anodes at high rate (over 5 C) during the fast ion insertion/extraction process. The present work demonstrates a robust strategy for a variety of (Sb-C, Bi-C, Sn-C, Ge-C, Sb-Bi-C) freestanding metal-carbon framework thin films via a space-confined superassembly (SCSA) strategy. The sodium-ion battery employing the Sb-C framework exhibits an unprecedented performance with a high specific capacity of 246 mAh g-1, long life cycle (5000 cycles), and superb capacity retention (almost 100%) at a high rate of 7.5 C (3.51A g-1). Further investigation indicates that the unique framework structure enables unusual reversible crystalline-phase transformation, guaranteeing the fast and long-cyclability sodium storage. This study may open an avenue to developing long-cycle-life and high-power SIBs for practical energy applications." @default.
- W2565394229 created "2017-01-06" @default.
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- W2565394229 date "2016-12-12" @default.
- W2565394229 modified "2023-10-15" @default.
- W2565394229 title "Direct Superassemblies of Freestanding Metal–Carbon Frameworks Featuring Reversible Crystalline-Phase Transformation for Electrochemical Sodium Storage" @default.
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- W2565394229 doi "https://doi.org/10.1021/jacs.6b10782" @default.
- W2565394229 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27936645" @default.
- W2565394229 hasPublicationYear "2016" @default.
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