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• W2565454927 endingPage "1448" @default.
• W2565454927 startingPage "1443" @default.
• W2565454927 abstract "Planar boron clusters B11−, B13+, B15+, and B19− have been introduced recently as molecular Wankel motors or tank treads. Here we present a universal mechanism for these dynamically fluxional clusters; that is, they are molecular rotors with inner wheels that rotate almost freely in pseudo-rotating outer bearings, analogous to rotating molecules trapped in pseudo-rotating cages. This mechanism has significant quantum mechanical consequences: the global-minimum structures of the clusters have C2v symmetry, whereas the wheels rotating in pseudo-rotating bearings generate rosette-type shapes with D9h, D10h, D11h, and D13h symmetries. The related rotational/pseudo-rotational energies appear with characteristic band structures, effecting the dynamics." @default.
• W2565454927 created "2017-01-06" @default.
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• W2565454927 date "2017-01-01" @default.
• W2565454927 modified "2023-10-18" @default.
• W2565454927 title "A universal mechanism of the planar boron rotors B₁₁⁻, B₁₃⁺, B₁₅⁺, and B₁₉⁻: inner wheels rotating in pseudo-rotating outer bearings" @default.
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• W2565454927 doi "https://doi.org/10.1039/c6nr09074e" @default.
• W2565454927 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/28094386" @default.
• W2565454927 hasPublicationYear "2017" @default.
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