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• W2565559211 endingPage "617" @default.
• W2565559211 startingPage "608" @default.
• W2565559211 abstract "Four new octanuclear Ru(II) cages (OC-1–OC-4) were synthesized from dinuclear p-cymene ruthenium(II) acceptors [Ru2(μ–η4-C2O4)(CH3OH)2(η6-p-cymene)2](O3SCF3)2 (A1), [Ru2(μ–η4-C6H2O4)(CH3OH)2(η6-p-cymene)2](O3SCF3)2 (A2), [Ru2(dhnq)(H2O)2(η6-p-cymene)2](O3SCF3)2 (A3), and [Ru2(dhtq)(H2O)2(η6-p-cymene)2](O3SCF3)2 (A4) separately with a tetradentate pyridyl ligand (L1) in methanol using coordination-driven self-assembly [L1= N,N,N′,N′-tetra(pyridin-4-yl)benzene-1,4-diamine]. The octanuclear cages are fully characterized by various spectroscopic techniques including single-crystal X-ray diffraction analysis of OC-4. The self-assembled cages show strong in vitro anticancer activity against human lung adenocarcinoma A549 and human cervical cancer HeLa cell lines as observed from the 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide assay. Of all the octanuclear cages, OC-3 exhibits remarkable anticancer activity against both cancer cell lines and is more active than that reported for cisplatin. The excellent anticancer activity of OC-3 and OC-4 highlights the importance of the synergistic effects of the spacer component of the dinuclear p-cymene Ru(II) acceptor clips." @default.
• W2565559211 created "2017-01-06" @default.
• W2565559211 creator A5020978468 @default.
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• W2565559211 creator A5075470922 @default.
• W2565559211 creator A5087522016 @default.
• W2565559211 creator A5025332456 @default.
• W2565559211 date "2016-12-20" @default.
• W2565559211 modified "2023-09-27" @default.
• W2565559211 title "Self-Assembly of Discrete Ru^II₈ Molecular Cages and Their in Vitro Anticancer Activity" @default.
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• W2565559211 doi "https://doi.org/10.1021/acs.inorgchem.6b02488" @default.
• W2565559211 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27997153" @default.
• W2565559211 hasPublicationYear "2016" @default.
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