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- W2565569802 abstract "Dark red and brick red transparent crystals of FeI4{GeI3Fe(CO)3}2 (1) and (GeI3)2Fe(CO)4 (2) were obtained by reacting GeI4 and Fe2(CO)9 or Fe3(CO)12 in a mixture of [BMIM]Cl and AlCl3 as ionic liquid (BMIm = 1-butyl-3-methylimidazolium). According to X-ray structure analysis based on single crystals, the title compounds exhibit cluster units with Fe–Ge bonds. FeI4{GeI3Fe(CO)3}2 consists of two GeI2I1/2-Fe(CO)3I2/2 units that are interlinked by a distorted octahedral FeI6/2 group. (GeI3)2Fe(CO)4 consists of two GeI3 units that are connected by a square planar Fe(CO)4 group with a linear Ge–Fe–Ge unit. Depending on the synthesis conditions, interestingly, (GeI3)2Fe(CO)4 crystallizes either in P21/n (2a) or in P1 (2b). 2a exhibits a more dense packing, whereas 2b exhibits shorter intermolecular I–I distances. Both title compounds are temperature labile and highly sensitive to oxygen, moisture and illumination, including X-ray irradiation. They decompose with release of CO in absence of certain CO atmosphere. In addition to crystal structure analysis the compounds were characterized by energy dispersive X-ray (EDX) analysis, thermogravimetry (TG) and infrared spectroscopy (FT-IR)." @default.
- W2565569802 created "2017-01-06" @default.
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- W2565569802 date "2016-12-16" @default.
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- W2565569802 title "Ionic-Liquid-Based Synthesis of the Germanium-Iron Carbonyls FeI<sub>4</sub>{GeI<sub>3</sub>Fe(CO)<sub>3</sub>}<sub>2</sub>and (GeI<sub>3</sub>)<sub>2</sub>Fe(CO)<sub>4</sub>" @default.
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- W2565569802 doi "https://doi.org/10.1002/zaac.201600380" @default.
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