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• W2565897724 endingPage "A6235" @default.
• W2565897724 startingPage "A6229" @default.
• W2565897724 abstract "We report about the electrochemical performance in the potential range 1.5 to 4.9 V of highly ordered, stoichiometric LiNi0.5Mn1.5O4 with spinel structure and tailored morphology. Structural and morphological parameters are optimized for obtaining maximum energy density in Li-ion cell applications. The effect of the discharge cutoff on the cathode capacity, cycling stability and coulombic efficiency is discussed. Li-rich structures with composition Li1+xNi0.5Mn1.5O4 (0 < × < 1) obtained via electrochemical lithiation are investigated via ex-situ XRD and SEM analysis. The results are compared with those obtained via a chemical lithiation method, showing that the phase transition from cubic LiNi0.5Mn1.5O4 to tetragonal Li2Ni0.5Mn1.5O4 occurs via a two-phase mechanism with no evidence of intermediate phases. The superior electrochemical performance of the synthesized cathode material is ascribed to its specific morphology that provides suitable properties for reduced side-reactions with the electrolyte and low impact of the volumetric changes during cycling." @default.
• W2565897724 created "2017-01-06" @default.
• W2565897724 creator A5003647300 @default.
• W2565897724 creator A5038730354 @default.
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• W2565897724 date "2016-12-13" @default.
• W2565897724 modified "2023-10-10" @default.
• W2565897724 title "Electrochemical Performance and Phase Transitions between 1.5 and 4.9 V of Highly-Ordered LiNi_0.5Mn_1.5O₄with Tailored Morphology: Influence of the Lithiation Method" @default.
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• W2565897724 doi "https://doi.org/10.1149/2.0291701jes" @default.
• W2565897724 hasPublicationYear "2016" @default.
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