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• W2567403192 abstract "Doped graphene-based cathode catalysts are considered as promising competitors for ORR, but their power density has been low compared to Pt-based cathodes, mainly due to poor mass-transport properties. A new electrocatalyst for PEMFCs, an iodine doped grahene was prepared, characterized, and tested and the results are presented in this paper. We report a hybrid derived electrocatalyst with increased electrochemical active area and enhanced mass-transport properties. The electrochemical performances of several configurations were tested and compared with a typical Pt/C cathode configuration. As a standalone catalyst, the iodine doped graphene gives a performance with 60% lower than if it is placed between gas diffusion layer and catalyst layer. If it is included as microporous layer, the electrochemical performances of the fuel cell are with 15% bigger in terms of power density than the typical fuel cell with the same Pt/C loading, proving the beneficial effect of the iodine doped graphene for the fuel cell in the ohmic and mass transfer region. Moreover, the hybrid cathode manufactured by commercial Pt/C together with the material with best proprieties, is tested in a H2-Air fuel cell and a power density of 0.55 W cm−2 at 0.52 V was obtained, which is superior to that of a commercial Pt-based cathode tested under identical conditions (0.46 W cm−2)." @default.
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• W2567403192 date "2019-09-01" @default.
• W2567403192 modified "2023-10-18" @default.
• W2567403192 title "Iodinated carbon materials for oxygen reduction reaction in proton exchange membrane fuel cell. Scalable synthesis and electrochemical performances" @default.
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• W2567403192 doi "https://doi.org/10.1016/j.arabjc.2016.12.002" @default.
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