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- W2567584269 abstract "The influences of molecular parameters such as molecular weight (Mw), the degree of substitution (DS) and especially the distribution of carboxymethyl substituents within the anhydroglucose unit (AGU) of carboxymethylcellulose (CMC) on the rheological properties of CMC solutions and the stability of acidified milk drinks (AMDs) induced by this cellulose ether have been comprehensively investigated and evaluated by LUMi-Sizer. The DS and the distribution of carboxymethyl substituents are characterized by means of 1H NMR spectroscopy using a set of acid-hydrolyzing CMC samples. A new CMC molecular parameter of Ri indicating the individual degree of substitution at the position of either C-2 (R2) or C-6 (R6) in AGU is proposed to evaluate the influence of distribution of carboxymethyl substituents on the stability of the milk drinks. It is found that the distribution of carboxymethyl substituents also plays a key role in the stability of AMDs. The stability of the drinks increases not only with increasing the Mw and DS but also with decreasing the R2 or increasing the R6 of CMC. This fact is explained on the basis of CMC with a higher individual DS at C-2 position resulting in higher electronegativity, thus increasing the electrostatic repulsion between CMC-adsorbed casein particles in the colloidal system, thereby contributing to a better stability to AMDs. These findings provide an insight into fabricating better stability of AMDs induced by CMC." @default.
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- W2567584269 date "2018-03-01" @default.
- W2567584269 modified "2023-10-08" @default.
- W2567584269 title "Impact of distribution of carboxymethyl substituents in the stabilizer of carboxymethyl cellulose on the stability of acidified milk drinks" @default.
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- W2567584269 doi "https://doi.org/10.1016/j.foodhyd.2016.12.034" @default.
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