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- W2567650099 abstract "We describe herein the first synthesis of silyl- and disilanyl-BODIPYs through transition-metal-catalyzed dehalosilylation of iodo-BODIPYs using a Pd(P(tBu)3 )2 /Et3 N/toluene system. Various mono- and bis-silyl-BODIPYs, mono- and bis-disilanyl-BODIPYs and bis-BODIPYs linked by silylene and SiOSi groups were synthesized by using this straightforward method. Silyl- and disilanyl-substitution significantly modifies the spectroscopic properties of the BODIPY, in which the fluorescence quantum yields of the silyl-BODIPYs are remarkably increased, whereas the emission spectra of disilanyl-BODIPYs are red-shifted due to effective σ(SiSi)-π(BODIPY) conjugation." @default.
- W2567650099 created "2017-01-06" @default.
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- W2567650099 date "2017-01-27" @default.
- W2567650099 modified "2023-09-29" @default.
- W2567650099 title "Silyl- and Disilanyl-BODIPYs: Synthesis via Catalytic Dehalosilylation and Spectroscopic Properties" @default.
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- W2567650099 doi "https://doi.org/10.1002/asia.201601637" @default.
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