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- W2567650736 abstract "An ultrasensitive fluorescent probe TPP was developed for the highly selective detection of thiophenols based on excited-state intramolecular proton transfer (ESIPT) mechanism, its synthesis through a simple straightforward combination of HBT fluorophore with 2,4-dinitrobenzene functional group. A kinetic study of TPP towards thiophenol displayed a fast response time (~150 s) and significant turn-on fluorescence enhancement (~60 fold). Selective and competitive experiments exhibited an excellent selectivity of TPP toward thiophenols over biothiols (Cys, GSH) and other aliphatic thiols or nucleophiles. Using this ultrasensitive probe (LOD, 1.05×10−8 M), we have successfully monitored and quantified highly toxic thiophenols in aqueous media and real-water samples." @default.
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- W2567650736 date "2017-04-01" @default.
- W2567650736 modified "2023-10-13" @default.
- W2567650736 title "An ultrasensitive fluorescent probe for rapid determination of thiophenols" @default.
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- W2567650736 doi "https://doi.org/10.1016/j.talanta.2016.12.074" @default.
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