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- W2567920903 abstract "Improving the processability and physical properties of sustainable biobased polymers using biobased fillers is essential to preserve its biodegradability and make them suitable for different end user applications. Herein, we report the use of spray-dried lignin-coated cellulose nanocrystals (L-CNCs), a biobased filler, to modify the rheological and thermo-mechanical properties of poly(lactic acid) (PLA) composites. The lignin coating on CNCs not only improved the dispersion of CNCs but also enhanced their interfacial interaction with the PLA matrix, resulting in a significant improvement in rheological and thermo-mechanical properties. The rheological percolation threshold concentration obtained by power law analysis for PLA/L-CNC composites was found to be 0.66 wt %, which is significantly lower than the reported values for other PLA/CNC composites. Such a low rheological percolation concentration of L-CNCs can be attributed to excellent dispersion of L-CNCs in the PLA matrix. Addition of only 0.5 wt % ..." @default.
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- W2567920903 date "2017-01-19" @default.
- W2567920903 modified "2023-10-13" @default.
- W2567920903 title "Rheological and Thermo-Mechanical Properties of Poly(lactic acid)/Lignin-Coated Cellulose Nanocrystal Composites" @default.
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- W2567920903 doi "https://doi.org/10.1021/acssuschemeng.6b02458" @default.
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