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- W2568388736 abstract "A spin state transition in a square planar coordinated iron was found in SrFeO2 and Sr3Fe2O5 under high pressure. This transition occurs as a consequence of enhanced Fe-Fe direct interactions between adjacent face-to-face FeO4 square planar units. We also found a pressure-induced structural transition in Sr3Fe2O5, which is viewed as a B1（NaCl structure） to B2（CsCl structure） structural transition. Such a B1-B2 structural transition generally occurs in intergrowth system consisting of rock-salt blocks and square-planar blocks, as found in A2MO3 （A＝Ca, Sr; M＝Cu, Pd）. An empirical relation between the structural transition pressure Ps and the ionic radius for the binary system holds well for the intergrowth structure, which indicates that the square-planar block is highly compressible along the out-of-plane direction." @default.
- W2568388736 created "2017-01-13" @default.
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- W2568388736 date "2016-01-01" @default.
- W2568388736 modified "2023-10-01" @default.
- W2568388736 title "Pressure-Induced Transitions in Square Planar Coordinate Metal Oxides" @default.
- W2568388736 doi "https://doi.org/10.5940/jcrsj.58.261" @default.
- W2568388736 hasPublicationYear "2016" @default.
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