FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2569486511> ?p ?o ?g. }

• W2569486511 endingPage "1644" @default.
• W2569486511 startingPage "1636" @default.
• W2569486511 abstract "For deeper understanding of the coupling of electronic processes with conformational motions, we exploit a tailored strategy to harness the excited-state planarization of N,N'-disubstituted dihydrodibenzo[a,c]phenazines by halting the structural evolution via a macrocyclization process. In this new approach, 9,14-diphenyl-9,14-dihydrodibenzo[a,c]phenazine (DPAC) is used as a prototype, in which the para sites of 9,14-diphenyl are systematically enclosed by a dialkoxybenzene-alkyl-ester or -ether linkage with different chain lengths, imposing various degrees of constraint to impede the structural deformation. Accordingly, a series of DPAC-n (n = 1-8) derivatives were synthesized, in which n correlates with the alkyl length, such that the strength of the spatial constraint decreases as n increases. The structures of DPAC-1, DPAC-3, DPAC-4, and DPAC-8 were identified by the X-ray crystal analysis. As a result, despite nearly identical absorption spectra (onset ∼400 nm) for DPAC-1-8, drastic chain-length dependent emission is observed, spanning from blue (n = 1, 2, ∼400 nm) and blue-green (n = 3-5, 500-550 nm) to green-orange (n = 6) and red (n = 7, 8, ∼610 nm) in various regular solvents. Comprehensive spectroscopic and dynamic studies, together with a computational approach, rationalized the associated excited-state structure responding to emission origin. Severing the linkage for DPAC-5 via lipase treatment releases the structural freedom and hence results in drastic changes of emission from blue-green (490 nm) to red (625 nm), showing the brightening prospect of these chemically locked DPAC-n in both fundamental studies and applications." @default.
• W2569486511 created "2017-01-13" @default.
• W2569486511 creator A5013737755 @default.
• W2569486511 creator A5017541508 @default.
• W2569486511 creator A5032004836 @default.
• W2569486511 creator A5048852254 @default.
• W2569486511 creator A5050844324 @default.
• W2569486511 creator A5054655736 @default.
• W2569486511 creator A5062819262 @default.
• W2569486511 creator A5078647459 @default.
• W2569486511 date "2017-01-24" @default.
• W2569486511 modified "2023-10-18" @default.
• W2569486511 title "Snapshotting the Excited-State Planarization of Chemically Locked <i>N</i>,<i>N</i>′-Disubstituted Dihydrodibenzo[<i>a</i>,<i>c</i>]phenazines" @default.
• W2569486511 cites W1713726940 @default.
• W2569486511 cites W1886421786 @default.
• W2569486511 cites W1971276614 @default.
• W2569486511 cites W1975374845 @default.
• W2569486511 cites W1995997812 @default.
• W2569486511 cites W2001309031 @default.
• W2569486511 cites W2015599181 @default.
• W2569486511 cites W2021792392 @default.
• W2569486511 cites W2026682825 @default.
• W2569486511 cites W2030557852 @default.
• W2569486511 cites W2058827285 @default.
• W2569486511 cites W2059471388 @default.
• W2569486511 cites W2075511300 @default.
• W2569486511 cites W2076271253 @default.
• W2569486511 cites W2110324274 @default.
• W2569486511 cites W2132576401 @default.
• W2569486511 cites W2164519484 @default.
• W2569486511 cites W2168036745 @default.
• W2569486511 cites W2177054697 @default.
• W2569486511 cites W2310953639 @default.
• W2569486511 cites W2322534724 @default.
• W2569486511 cites W2325579237 @default.
• W2569486511 cites W2342366418 @default.
• W2569486511 cites W2413673325 @default.
• W2569486511 cites W2470338734 @default.
• W2569486511 cites W2487091079 @default.
• W2569486511 cites W2514279849 @default.
• W2569486511 cites W2951222120 @default.
• W2569486511 cites W4211199126 @default.
• W2569486511 cites W6340884 @default.
• W2569486511 cites W87248137 @default.
• W2569486511 doi "https://doi.org/10.1021/jacs.6b11789" @default.
• W2569486511 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/28072523" @default.
• W2569486511 hasPublicationYear "2017" @default.
• W2569486511 type Work @default.
• W2569486511 sameAs 2569486511 @default.
• W2569486511 citedByCount "117" @default.
• W2569486511 countsByYear W25694865112017 @default.
• W2569486511 countsByYear W25694865112018 @default.
• W2569486511 countsByYear W25694865112019 @default.
• W2569486511 countsByYear W25694865112020 @default.
• W2569486511 countsByYear W25694865112021 @default.
• W2569486511 countsByYear W25694865112022 @default.
• W2569486511 countsByYear W25694865112023 @default.
• W2569486511 crossrefType "journal-article" @default.
• W2569486511 hasAuthorship W2569486511A5013737755 @default.
• W2569486511 hasAuthorship W2569486511A5017541508 @default.
• W2569486511 hasAuthorship W2569486511A5032004836 @default.
• W2569486511 hasAuthorship W2569486511A5048852254 @default.
• W2569486511 hasAuthorship W2569486511A5050844324 @default.
• W2569486511 hasAuthorship W2569486511A5054655736 @default.
• W2569486511 hasAuthorship W2569486511A5062819262 @default.
• W2569486511 hasAuthorship W2569486511A5078647459 @default.
• W2569486511 hasConcept C121332964 @default.
• W2569486511 hasConcept C178790620 @default.
• W2569486511 hasConcept C180088628 @default.
• W2569486511 hasConcept C181500209 @default.
• W2569486511 hasConcept C184779094 @default.
• W2569486511 hasConcept C185592680 @default.
• W2569486511 hasConcept C2778370995 @default.
• W2569486511 hasConcept C2779227376 @default.
• W2569486511 hasConcept C2780263894 @default.
• W2569486511 hasConcept C2780407432 @default.
• W2569486511 hasConcept C71240020 @default.
• W2569486511 hasConcept C8010536 @default.
• W2569486511 hasConceptScore W2569486511C121332964 @default.
• W2569486511 hasConceptScore W2569486511C178790620 @default.
• W2569486511 hasConceptScore W2569486511C180088628 @default.
• W2569486511 hasConceptScore W2569486511C181500209 @default.
• W2569486511 hasConceptScore W2569486511C184779094 @default.
• W2569486511 hasConceptScore W2569486511C185592680 @default.
• W2569486511 hasConceptScore W2569486511C2778370995 @default.
• W2569486511 hasConceptScore W2569486511C2779227376 @default.
• W2569486511 hasConceptScore W2569486511C2780263894 @default.
• W2569486511 hasConceptScore W2569486511C2780407432 @default.
• W2569486511 hasConceptScore W2569486511C71240020 @default.
• W2569486511 hasConceptScore W2569486511C8010536 @default.
• W2569486511 hasFunder F4320321540 @default.
• W2569486511 hasIssue "4" @default.
• W2569486511 hasLocation W25694865111 @default.
• W2569486511 hasLocation W25694865112 @default.
• W2569486511 hasOpenAccess W2569486511 @default.
• W2569486511 hasPrimaryLocation W25694865111 @default.
• W2569486511 hasRelatedWork W1974496386 @default.
• W2569486511 hasRelatedWork W2082989531 @default.

• next