FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2569756057> ?p ?o ?g. }

• W2569756057 endingPage "120" @default.
• W2569756057 startingPage "115" @default.
• W2569756057 abstract "Thermal runaway in chemical batch and semibatch reactors is one of the major plagues in fine chemical, pharmaceutical and plastic industries. Quite often the root cause of such events is a poor knowledge of the process kinetics and thermodynamics. For this reason, accidents continue to occur with a high frequency in both European and American countries. The present work is focused on the accident occurred in 2006 at Synthron Inc. (Morganton, NC), an American company that manufactured a great variety of powder coatings and paint additives. The accident has been originated by a runaway reaction and subsequent vapor cloud explosion (that killed one worker and injured 14 others) due to a wrong scaling-up of the original process recipe. Particularly, the standard synthesis was carried out in a 1,500 gallon semibatch reactor by polymerizing liquid acrylic monomers in a high flammable solvent blend. On the day of the accident, in order to produce slightly more of the desired product, plant managers decided to scale-up the process recipe in a single larger batch. In order to perform the synthesis in the same time of the standard recipe, they also decided to load almost all of the additional monomer required into the initial reactor charge: that is, using a quasi-batch operating mode. Unfortunately, adding all the monomer in one shot, more than doubled the rate of energy release in the reactor, exceeding the cooling capacity of the equipped condenser and causing a runaway reaction. The reactor pressure increased rapidly. Solvent vapors, vented from the reactor’s rupture disc, formed a flammable cloud inside the building, found an ignition source and, finally, resulted in a violent explosion. This work presents a detailed reconstruction of the dynamics of the accident occurred at Synthron Inc. using all data collected by the U.S. Chemical Safety Board (CSB) and implementing a detailed mathematical model capable of describing monomer conversion, temperature and pressure evolution inside the reactor together with the condenser efficiency. Particularly, all constitutive equations of material and energy balance, dosing policies and mixing rules have been considered. Results arising from simulations have been found to be in good agreement with both CSB collected data and successive reconstructions." @default.
• W2569756057 created "2017-01-13" @default.
• W2569756057 creator A5020615351 @default.
• W2569756057 creator A5031654865 @default.
• W2569756057 creator A5054999748 @default.
• W2569756057 creator A5059798421 @default.
• W2569756057 creator A5069604646 @default.
• W2569756057 creator A5082795376 @default.
• W2569756057 date "2014-04-20" @default.
• W2569756057 modified "2023-09-27" @default.
• W2569756057 title "Runaway reactions and vapor cloud explosions: the synthron case study" @default.
• W2569756057 doi "https://doi.org/10.3303/cet1436020" @default.
• W2569756057 hasPublicationYear "2014" @default.
• W2569756057 type Work @default.
• W2569756057 sameAs 2569756057 @default.
• W2569756057 citedByCount "0" @default.
• W2569756057 crossrefType "journal-article" @default.
• W2569756057 hasAuthorship W2569756057A5020615351 @default.
• W2569756057 hasAuthorship W2569756057A5031654865 @default.
• W2569756057 hasAuthorship W2569756057A5054999748 @default.
• W2569756057 hasAuthorship W2569756057A5059798421 @default.
• W2569756057 hasAuthorship W2569756057A5069604646 @default.
• W2569756057 hasAuthorship W2569756057A5082795376 @default.
• W2569756057 hasConcept C116915560 @default.
• W2569756057 hasConcept C120665830 @default.
• W2569756057 hasConcept C121332964 @default.
• W2569756057 hasConcept C127413603 @default.
• W2569756057 hasConcept C163258240 @default.
• W2569756057 hasConcept C185592680 @default.
• W2569756057 hasConcept C18762648 @default.
• W2569756057 hasConcept C192562407 @default.
• W2569756057 hasConcept C21880701 @default.
• W2569756057 hasConcept C2778671685 @default.
• W2569756057 hasConcept C2780934509 @default.
• W2569756057 hasConcept C2982854487 @default.
• W2569756057 hasConcept C31892906 @default.
• W2569756057 hasConcept C31903555 @default.
• W2569756057 hasConcept C39432304 @default.
• W2569756057 hasConcept C42360764 @default.
• W2569756057 hasConcept C548081761 @default.
• W2569756057 hasConcept C555008776 @default.
• W2569756057 hasConcept C72688512 @default.
• W2569756057 hasConcept C77595967 @default.
• W2569756057 hasConcept C78519656 @default.
• W2569756057 hasConcept C97355855 @default.
• W2569756057 hasConceptScore W2569756057C116915560 @default.
• W2569756057 hasConceptScore W2569756057C120665830 @default.
• W2569756057 hasConceptScore W2569756057C121332964 @default.
• W2569756057 hasConceptScore W2569756057C127413603 @default.
• W2569756057 hasConceptScore W2569756057C163258240 @default.
• W2569756057 hasConceptScore W2569756057C185592680 @default.
• W2569756057 hasConceptScore W2569756057C18762648 @default.
• W2569756057 hasConceptScore W2569756057C192562407 @default.
• W2569756057 hasConceptScore W2569756057C21880701 @default.
• W2569756057 hasConceptScore W2569756057C2778671685 @default.
• W2569756057 hasConceptScore W2569756057C2780934509 @default.
• W2569756057 hasConceptScore W2569756057C2982854487 @default.
• W2569756057 hasConceptScore W2569756057C31892906 @default.
• W2569756057 hasConceptScore W2569756057C31903555 @default.
• W2569756057 hasConceptScore W2569756057C39432304 @default.
• W2569756057 hasConceptScore W2569756057C42360764 @default.
• W2569756057 hasConceptScore W2569756057C548081761 @default.
• W2569756057 hasConceptScore W2569756057C555008776 @default.
• W2569756057 hasConceptScore W2569756057C72688512 @default.
• W2569756057 hasConceptScore W2569756057C77595967 @default.
• W2569756057 hasConceptScore W2569756057C78519656 @default.
• W2569756057 hasConceptScore W2569756057C97355855 @default.
• W2569756057 hasLocation W25697560571 @default.
• W2569756057 hasOpenAccess W2569756057 @default.
• W2569756057 hasPrimaryLocation W25697560571 @default.
• W2569756057 hasRelatedWork W1517848810 @default.
• W2569756057 hasRelatedWork W185703492 @default.
• W2569756057 hasRelatedWork W1973768592 @default.
• W2569756057 hasRelatedWork W1983129871 @default.
• W2569756057 hasRelatedWork W2003919169 @default.
• W2569756057 hasRelatedWork W2058166703 @default.
• W2569756057 hasRelatedWork W2089036519 @default.
• W2569756057 hasRelatedWork W2176192104 @default.
• W2569756057 hasRelatedWork W2359866823 @default.
• W2569756057 hasRelatedWork W2364387748 @default.
• W2569756057 hasRelatedWork W2393067514 @default.
• W2569756057 hasRelatedWork W2436242549 @default.
• W2569756057 hasRelatedWork W252087676 @default.
• W2569756057 hasRelatedWork W2580974764 @default.
• W2569756057 hasRelatedWork W2781238106 @default.
• W2569756057 hasRelatedWork W2912213405 @default.
• W2569756057 hasRelatedWork W38467184 @default.
• W2569756057 hasRelatedWork W762172360 @default.
• W2569756057 hasRelatedWork W2929103555 @default.
• W2569756057 hasRelatedWork W3159619418 @default.
• W2569756057 hasVolume "36" @default.
• W2569756057 isParatext "false" @default.
• W2569756057 isRetracted "false" @default.
• W2569756057 magId "2569756057" @default.
• W2569756057 workType "article" @default.