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• W2569821609 endingPage "434" @default.
• W2569821609 startingPage "424" @default.
• W2569821609 abstract "Methyl anion abstraction from (o-diphenylphosphino)phenyl(methyl)zirconocene by trityl tetrakis(pentafluorophenyl)borate gives the o-phenylene-bridged Zr+/P system 10. It behaves toward a variety of reagents as a typical Zr+/P frustrated Lewis pair (FLP). It undergoes cooperative 1,4-addition reactions to some chalcone derivatives and adds in a 1,2-fashion to a variety of organic carbonyls and to several heterocumulenes. The reactive Zr–C σ bond of the FLP 10 remains intact in these reactions. Complex 10 splits dihydrogen, but subsequently the Zr–C σ bond is protonolytically cleaved in this case. Only a few special reagents, among them carbon monoxide, undergo the usual insertion reaction into the Zr–C(aryl) σ-bond of the Zr+/P system 10." @default.
• W2569821609 created "2017-01-13" @default.
• W2569821609 creator A5034751002 @default.
• W2569821609 creator A5034807035 @default.
• W2569821609 creator A5048542589 @default.
• W2569821609 creator A5069157108 @default.
• W2569821609 date "2017-01-09" @default.
• W2569821609 modified "2023-10-03" @default.
• W2569821609 title "Frustrated Lewis Pair vs Metal–Carbon σ-Bond Insertion Chemistry at an <i>o</i>-Phenylene-Bridged Cp₂Zr⁺/PPh₂ System" @default.
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